Synthesis and crystal structure of (CN3H6)2[UO2(OH)2(NCS)]NO3 and β-Cs3[UO2(NCS)5] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-03

AUTHORS

V. N. Serezhkin, E. V. Peresypkina, M. O. Karasev, A. V. Virovets, L. B. Serezhkina

ABSTRACT

Compounds (CN3H6)2[UO2(OH)2(NCS)]NO3 (I) and β-Cs3[UO2(NCS)5] (II) are synthesized and studied by IR spectroscopy and single-crystal X-ray diffraction. I and II crystallize in the orthorhombic system. For I, a = 12.2015(13) Å, b = 7.3295(8) Å, c = 16.310(2) Å, space group Pnma, Z = 4, and R = 0.0327; for II, a = 21.7891(6) Å, b = 13.5120(3) Å, c = 6.8522(2) Å, space group Pnma, Z = 4, and R = 0.0268. In structure I, complex groups form infinite chains [UO2(OH)2(NCS)]nn− belonging to the AM22M1 crystal chemical group of uranyl complexes (A = UO22+, M2 = OH−, and M1 = NCS−). The main structural elements of crystals II are mononuclear [UO2(NCS)5]3− groups belonging to the AM51 group of uranyl complexes (A = UO22+ and M1 = NCS−). In I and II, uranium-containing complexes are connected with outer-sphere cations by electrostatic interactions, and in I a system of hydrogen bonds also contributes to their binding. Specific features of the packing of complex [UO2(NCS)5]3− groups in the structures of two modifications of Cs3[UO2(NCS)5] are discussed. More... »

PAGES

196-201

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063774514020199

DOI

http://dx.doi.org/10.1134/s1063774514020199

DIMENSIONS

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