Structure and magnetic properties of heterometallic coordination carboxylate polymers with cobalt and lithium atoms View Full Text


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Article Info

DATE

2011-09-18

AUTHORS

I. E. Evstifeev, M. A. Kiskin, A. S. Bogomyakov, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

Reactions between lithium pivalate and cobalt coordination polymers [Co5(OH2)(OH)(Piv)9)L1)4]n (I) and [Co2(OH2)(Piv)4(L2)2]n (II), where Piv—is the pivalate anion, L1 is pyrazine, and L2 is pyrimidine, result in new heterometallic polymers {[Li2Co2(Piv)6(L1)2]2MeCN}n (III), {[Li2Co2(Piv)6(L2)]0.5MeCN}n (IV), and [Li2Co2(Piv)6(L2)2]n (V). The resulting compounds contain tetra-nuclear {Li2Co2(Piv)6} fragments connected by neutral bridging ligands (pyrazine or pyrimidine) into layer structures. Crystal structures III–V are determined, and the magnetic properties of III and IV are studied. More... »

PAGES

842

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1134/s1063774511050087

DOI

http://dx.doi.org/10.1134/s1063774511050087

DIMENSIONS

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