Synthesis and crystal structure of [(C7H10N)2]2+ [Sb2Cl8]2−1 View Full Text


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Article Info

DATE

2010-12

AUTHORS

Yun Guo, Miao Zhang, Liang Shen, Ying-Ying Jin, Zhi-Min Jin

ABSTRACT

The reaction of 2,6-dimethylpyridine with SbCl3 and HCl affords the title compound, the structure of which is ascertained by X-ray diffraction. The unit cell consists of one bridged Sb2Cl82− anion and two 2,6-dimethylpyridinium cations. The trivalent antimony ion is bonded not only directly to chlorine anions, but also is coordinated with chlorine anions by secondary bonds. In the crystal, there exists infinite coordinated chains of [Sb2Cl8]n2n− anions running along the a axis, which link 2,6-dimethylpyridinium cations by N-H…Cl hydrogen bonds. More... »

PAGES

1194-1197

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063774510070151

DOI

http://dx.doi.org/10.1134/s1063774510070151

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039444079


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