Synthesis and structure of (Rb0.50Ba0.25)[UO2(CH3COO)3] View Full Text


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Article Info

DATE

2010-03

AUTHORS

L. B. Serezhkina, E. V. Peresypkina, A. V. Virovets, V. V. Klepov

ABSTRACT

A new compound (Rb0.50Ba0.25)[UO2(CH3COO)3] is synthesized and its crystal structure is studied by X-ray diffraction. The compound crystallizes in the form of yellow plates belonging to the cubic crystal system. The unit cell parameter a = 17.0367(1) Å, V = 4944.89(5) Å3, space group I3d, Z = 16, and R = 0.0182. The coordination polyhedron of the uranium atom is a hexagonal bipyramid with oxygen atoms of three acetate groups and the uranyl group in the vertices. The crystal chemical formula of the uranium-containing group is AB301(A = UO22+, B01 = CH3COO−). The oxygen atoms of the acetate groups that enter the coordination polyhedron of uranium are bound to barium and rubidium atoms. More... »

PAGES

221-223

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063774510020094

DOI

http://dx.doi.org/10.1134/s1063774510020094

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033001265


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