Crystal structure of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] · 1.25H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-07

AUTHORS

L. B. Serezhkina, E. V. Peresypkina, A. V. Virovets, N. A. Neklyudova, D. V. Pushkin

ABSTRACT

Synthesis and X-ray diffraction study of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] · 1.25H2O single crystals have been performed. This compound is crystallized in the orthorhombic system, with the unit-cell parameters a = 45.2646(8) Å, b = 57.7359(11) Å, c = 7.9244(3) Å, sp. gr. Fdd2, Z = 16, V = 20 709.6(10) Å3, and R = 0.0477. The uranium-containing structural units of the crystals are one-core groups of the [UO2(C2O4)2(NCS)]3− composition, belonging to the crystallochemical group AB201M1 (A = UO2+2, B01 = C2O42−, M1 = NCS−) of uranyl complexes. The uranium-containing complexes are connected into a three-dimensional framework owing to the electrostatic interactions with the outer-sphere cations and a system of hydrogen bonds. More... »

PAGES

651-654

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1063774508040160

DOI

http://dx.doi.org/10.1134/s1063774508040160

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001336125


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Samara State University", 
          "id": "https://www.grid.ac/institutes/grid.113032.2", 
          "name": [
            "Samara State University, ul. Akademika Pavlova 1, 443011, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Serezhkina", 
        "givenName": "L. B.", 
        "id": "sg:person.01021147215.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01021147215.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 8, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Peresypkina", 
        "givenName": "E. V.", 
        "id": "sg:person.0623032534.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0623032534.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 8, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Virovets", 
        "givenName": "A. V.", 
        "id": "sg:person.0642271552.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642271552.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State University", 
          "id": "https://www.grid.ac/institutes/grid.113032.2", 
          "name": [
            "Samara State University, ul. Akademika Pavlova 1, 443011, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Neklyudova", 
        "givenName": "N. A.", 
        "id": "sg:person.07370330741.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07370330741.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Samara State University", 
          "id": "https://www.grid.ac/institutes/grid.113032.2", 
          "name": [
            "Samara State University, ul. Akademika Pavlova 1, 443011, Samara, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pushkin", 
        "givenName": "D. V.", 
        "id": "sg:person.0671454740.85", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0671454740.85"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/1521-3773(20020104)41:1<48::aid-anie48>3.0.co;2-u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021675147"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-07", 
    "datePublishedReg": "2008-07-01", 
    "description": "Synthesis and X-ray diffraction study of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] \u00b7 1.25H2O single crystals have been performed. This compound is crystallized in the orthorhombic system, with the unit-cell parameters a = 45.2646(8) \u00c5, b = 57.7359(11) \u00c5, c = 7.9244(3) \u00c5, sp. gr. Fdd2, Z = 16, V = 20 709.6(10) \u00c53, and R = 0.0477. The uranium-containing structural units of the crystals are one-core groups of the [UO2(C2O4)2(NCS)]3\u2212 composition, belonging to the crystallochemical group AB201M1 (A = UO2+2, B01 = C2O42\u2212, M1 = NCS\u2212) of uranyl complexes. The uranium-containing complexes are connected into a three-dimensional framework owing to the electrostatic interactions with the outer-sphere cations and a system of hydrogen bonds.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1063774508040160", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1295066", 
        "issn": [
          "0023-4761", 
          "0038-5638"
        ], 
        "name": "Crystallography Reports", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "53"
      }
    ], 
    "name": "Crystal structure of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] \u00b7 1.25H2O", 
    "pagination": "651-654", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "065db2435c6fc32a190d2101fc6023e5213e43d8095e1d0f9865db4ef69ee1e2"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1063774508040160"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1001336125"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1063774508040160", 
      "https://app.dimensions.ai/details/publication/pub.1001336125"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T21:34", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000502.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1063774508040160"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1063774508040160'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1063774508040160'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1063774508040160'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1063774508040160'


 

This table displays all metadata directly associated to this object as RDF triples.

95 TRIPLES      21 PREDICATES      28 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1063774508040160 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N92ac06f7120b4298b6c94062aaf83a1e
4 schema:citation https://doi.org/10.1002/1521-3773(20020104)41:1<48::aid-anie48>3.0.co;2-u
5 schema:datePublished 2008-07
6 schema:datePublishedReg 2008-07-01
7 schema:description Synthesis and X-ray diffraction study of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] · 1.25H2O single crystals have been performed. This compound is crystallized in the orthorhombic system, with the unit-cell parameters a = 45.2646(8) Å, b = 57.7359(11) Å, c = 7.9244(3) Å, sp. gr. Fdd2, Z = 16, V = 20 709.6(10) Å3, and R = 0.0477. The uranium-containing structural units of the crystals are one-core groups of the [UO2(C2O4)2(NCS)]3− composition, belonging to the crystallochemical group AB201M1 (A = UO2+2, B01 = C2O42−, M1 = NCS−) of uranyl complexes. The uranium-containing complexes are connected into a three-dimensional framework owing to the electrostatic interactions with the outer-sphere cations and a system of hydrogen bonds.
8 schema:genre research_article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N7e931a3ec2bd44c9a3626501ec2cb260
12 Nac5c768ef0af411e9c9e2177328b8835
13 sg:journal.1295066
14 schema:name Crystal structure of {NH2C(NHC6H5)2}3[UO2(C2O4)2(NCS)] · 1.25H2O
15 schema:pagination 651-654
16 schema:productId N151ab2e5969d4c7fb9f3831aacf5cc80
17 N57a5e2ec62a447788f7e4dd1a944c3ab
18 N906df4b0f83b4ec3ad041efd75748e2d
19 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001336125
20 https://doi.org/10.1134/s1063774508040160
21 schema:sdDatePublished 2019-04-10T21:34
22 schema:sdLicense https://scigraph.springernature.com/explorer/license/
23 schema:sdPublisher N321f4684618a47b0890c454eaca665a4
24 schema:url http://link.springer.com/10.1134%2FS1063774508040160
25 sgo:license sg:explorer/license/
26 sgo:sdDataset articles
27 rdf:type schema:ScholarlyArticle
28 N090d0fbd0b504d898c78718e8889aa3d rdf:first sg:person.07370330741.16
29 rdf:rest N3d0d5efc3cdb4853bf8fb30b9f331bd0
30 N151ab2e5969d4c7fb9f3831aacf5cc80 schema:name doi
31 schema:value 10.1134/s1063774508040160
32 rdf:type schema:PropertyValue
33 N321f4684618a47b0890c454eaca665a4 schema:name Springer Nature - SN SciGraph project
34 rdf:type schema:Organization
35 N3d0d5efc3cdb4853bf8fb30b9f331bd0 rdf:first sg:person.0671454740.85
36 rdf:rest rdf:nil
37 N57a5e2ec62a447788f7e4dd1a944c3ab schema:name readcube_id
38 schema:value 065db2435c6fc32a190d2101fc6023e5213e43d8095e1d0f9865db4ef69ee1e2
39 rdf:type schema:PropertyValue
40 N7e931a3ec2bd44c9a3626501ec2cb260 schema:issueNumber 4
41 rdf:type schema:PublicationIssue
42 N906df4b0f83b4ec3ad041efd75748e2d schema:name dimensions_id
43 schema:value pub.1001336125
44 rdf:type schema:PropertyValue
45 N92ac06f7120b4298b6c94062aaf83a1e rdf:first sg:person.01021147215.08
46 rdf:rest Nf722ca9852e0487fb8925103946b4ac7
47 Nac5c768ef0af411e9c9e2177328b8835 schema:volumeNumber 53
48 rdf:type schema:PublicationVolume
49 Nd1e45ff17b654ad69d07104fa8486596 rdf:first sg:person.0642271552.29
50 rdf:rest N090d0fbd0b504d898c78718e8889aa3d
51 Nf722ca9852e0487fb8925103946b4ac7 rdf:first sg:person.0623032534.48
52 rdf:rest Nd1e45ff17b654ad69d07104fa8486596
53 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
54 schema:name Chemical Sciences
55 rdf:type schema:DefinedTerm
56 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
57 schema:name Inorganic Chemistry
58 rdf:type schema:DefinedTerm
59 sg:journal.1295066 schema:issn 0023-4761
60 0038-5638
61 schema:name Crystallography Reports
62 rdf:type schema:Periodical
63 sg:person.01021147215.08 schema:affiliation https://www.grid.ac/institutes/grid.113032.2
64 schema:familyName Serezhkina
65 schema:givenName L. B.
66 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01021147215.08
67 rdf:type schema:Person
68 sg:person.0623032534.48 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
69 schema:familyName Peresypkina
70 schema:givenName E. V.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0623032534.48
72 rdf:type schema:Person
73 sg:person.0642271552.29 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
74 schema:familyName Virovets
75 schema:givenName A. V.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642271552.29
77 rdf:type schema:Person
78 sg:person.0671454740.85 schema:affiliation https://www.grid.ac/institutes/grid.113032.2
79 schema:familyName Pushkin
80 schema:givenName D. V.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0671454740.85
82 rdf:type schema:Person
83 sg:person.07370330741.16 schema:affiliation https://www.grid.ac/institutes/grid.113032.2
84 schema:familyName Neklyudova
85 schema:givenName N. A.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07370330741.16
87 rdf:type schema:Person
88 https://doi.org/10.1002/1521-3773(20020104)41:1<48::aid-anie48>3.0.co;2-u schema:sameAs https://app.dimensions.ai/details/publication/pub.1021675147
89 rdf:type schema:CreativeWork
90 https://www.grid.ac/institutes/grid.113032.2 schema:alternateName Samara State University
91 schema:name Samara State University, ul. Akademika Pavlova 1, 443011, Samara, Russia
92 rdf:type schema:Organization
93 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
94 schema:name Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 8, 630090, Novosibirsk, Russia
95 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...