Investigation of X-ray natural circular dichroism in a CsCuCl3 single crystal: Theory and experiment View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-05

AUTHORS

A. Rogalev, J. Goulon, F. Wilhelm, K. A. Kozlovskaya, E. N. Ovchinnikova, L. V. Soboleva, A. F. Konstantinova, V. E. Dmitrienko

ABSTRACT

X-ray natural circular dichroism in the near-Cu K edge in a CsCuCl3 single crystal, caused by dipole-quadrupole (E1E2) transitions between electronic states of different parity, has been experimentally and theoretically investigated. Numerical simulation of the experimental X-ray absorption spectrum and circular dichroism has been performed. It is established that a circular dichroism signal is observed in the pre-edge spectral region; therefore, it is mainly due to the localized electronic p-d states. More... »

PAGES

384-390

References to SciGraph publications

  • 2001-10-05. Instrumentation Developments for Polarization Dependent X-ray Spectroscopies in MAGNETISM AND SYNCHROTRON RADIATION
  • 1998-07. Calculation of X-ray natural circular dichroism in THE EUROPEAN PHYSICAL JOURNAL B
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1063774508030048

    DOI

    http://dx.doi.org/10.1134/s1063774508030048

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1001956182


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "European Synchrotron Radiation Facility, Grenoble, France", 
              "id": "http://www.grid.ac/institutes/grid.5398.7", 
              "name": [
                "European Synchrotron Radiation Facility, Grenoble, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Rogalev", 
            "givenName": "A.", 
            "id": "sg:person.01312655701.44", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01312655701.44"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "European Synchrotron Radiation Facility, Grenoble, France", 
              "id": "http://www.grid.ac/institutes/grid.5398.7", 
              "name": [
                "European Synchrotron Radiation Facility, Grenoble, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Goulon", 
            "givenName": "J.", 
            "id": "sg:person.0647036243.35", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0647036243.35"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "European Synchrotron Radiation Facility, Grenoble, France", 
              "id": "http://www.grid.ac/institutes/grid.5398.7", 
              "name": [
                "European Synchrotron Radiation Facility, Grenoble, France"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Wilhelm", 
            "givenName": "F.", 
            "id": "sg:person.01327015542.12", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01327015542.12"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Moscow State University, 119992, Leninskie gory, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.14476.30", 
              "name": [
                "Moscow State University, 119992, Leninskie gory, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kozlovskaya", 
            "givenName": "K. A.", 
            "id": "sg:person.07727214467.39", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07727214467.39"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Moscow State University, 119992, Leninskie gory, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.14476.30", 
              "name": [
                "Moscow State University, 119992, Leninskie gory, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Ovchinnikova", 
            "givenName": "E. N.", 
            "id": "sg:person.012037735004.20", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012037735004.20"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninski\u012d pr. 59, 119333, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninski\u012d pr. 59, 119333, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Soboleva", 
            "givenName": "L. V.", 
            "id": "sg:person.014050706115.26", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014050706115.26"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninski\u012d pr. 59, 119333, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninski\u012d pr. 59, 119333, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Konstantinova", 
            "givenName": "A. F.", 
            "id": "sg:person.010452076575.45", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010452076575.45"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninski\u012d pr. 59, 119333, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninski\u012d pr. 59, 119333, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Dmitrienko", 
            "givenName": "V. E.", 
            "id": "sg:person.0742761172.43", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0742761172.43"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/3-540-44954-x_3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036773883", 
              "https://doi.org/10.1007/3-540-44954-x_3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/s100510050344", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015159057", 
              "https://doi.org/10.1007/s100510050344"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2008-05", 
        "datePublishedReg": "2008-05-01", 
        "description": "X-ray natural circular dichroism in the near-Cu K edge in a CsCuCl3 single crystal, caused by dipole-quadrupole (E1E2) transitions between electronic states of different parity, has been experimentally and theoretically investigated. Numerical simulation of the experimental X-ray absorption spectrum and circular dichroism has been performed. It is established that a circular dichroism signal is observed in the pre-edge spectral region; therefore, it is mainly due to the localized electronic p-d states.", 
        "genre": "article", 
        "id": "sg:pub.10.1134/s1063774508030048", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1295066", 
            "issn": [
              "0023-4761", 
              "0038-5638"
            ], 
            "name": "Crystallography Reports", 
            "publisher": "Pleiades Publishing", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "53"
          }
        ], 
        "keywords": [
          "ray natural circular dichroism", 
          "natural circular dichroism", 
          "circular dichroism", 
          "ray absorption spectra", 
          "Cu K edge", 
          "single crystals", 
          "circular dichroism signal", 
          "electronic states", 
          "spectral region", 
          "dichroism signal", 
          "absorption spectra", 
          "dichroism", 
          "different parities", 
          "crystals", 
          "numerical simulations", 
          "spectra", 
          "state", 
          "transition", 
          "edge", 
          "theory", 
          "parity", 
          "simulations", 
          "signals", 
          "experiments", 
          "region", 
          "investigation", 
          "K edge", 
          "CsCuCl3 single crystals", 
          "dipole-quadrupole (E1E2) transitions", 
          "pre-edge spectral region"
        ], 
        "name": "Investigation of X-ray natural circular dichroism in a CsCuCl3 single crystal: Theory and experiment", 
        "pagination": "384-390", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1001956182"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s1063774508030048"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s1063774508030048", 
          "https://app.dimensions.ai/details/publication/pub.1001956182"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2021-12-01T19:21", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_469.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1134/s1063774508030048"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1063774508030048'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1063774508030048'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1063774508030048'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1063774508030048'


     

    This table displays all metadata directly associated to this object as RDF triples.

    151 TRIPLES      22 PREDICATES      58 URIs      48 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s1063774508030048 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author Nf045cb6c94b74fdf9863695f2ed19126
    4 schema:citation sg:pub.10.1007/3-540-44954-x_3
    5 sg:pub.10.1007/s100510050344
    6 schema:datePublished 2008-05
    7 schema:datePublishedReg 2008-05-01
    8 schema:description X-ray natural circular dichroism in the near-Cu K edge in a CsCuCl3 single crystal, caused by dipole-quadrupole (E1E2) transitions between electronic states of different parity, has been experimentally and theoretically investigated. Numerical simulation of the experimental X-ray absorption spectrum and circular dichroism has been performed. It is established that a circular dichroism signal is observed in the pre-edge spectral region; therefore, it is mainly due to the localized electronic p-d states.
    9 schema:genre article
    10 schema:inLanguage en
    11 schema:isAccessibleForFree false
    12 schema:isPartOf Nf390c7e9d39e4582bc8d95db78753967
    13 Nf8c9213f98ed4fc498a435a4117bde50
    14 sg:journal.1295066
    15 schema:keywords CsCuCl3 single crystals
    16 Cu K edge
    17 K edge
    18 absorption spectra
    19 circular dichroism
    20 circular dichroism signal
    21 crystals
    22 dichroism
    23 dichroism signal
    24 different parities
    25 dipole-quadrupole (E1E2) transitions
    26 edge
    27 electronic states
    28 experiments
    29 investigation
    30 natural circular dichroism
    31 numerical simulations
    32 parity
    33 pre-edge spectral region
    34 ray absorption spectra
    35 ray natural circular dichroism
    36 region
    37 signals
    38 simulations
    39 single crystals
    40 spectra
    41 spectral region
    42 state
    43 theory
    44 transition
    45 schema:name Investigation of X-ray natural circular dichroism in a CsCuCl3 single crystal: Theory and experiment
    46 schema:pagination 384-390
    47 schema:productId N504930961e9249d3a215635af926ece2
    48 N7d3f54f8111b4416b2320eccdcb3a2fa
    49 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001956182
    50 https://doi.org/10.1134/s1063774508030048
    51 schema:sdDatePublished 2021-12-01T19:21
    52 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    53 schema:sdPublisher Nb9f5f264d554403e8b930425d1a7364c
    54 schema:url https://doi.org/10.1134/s1063774508030048
    55 sgo:license sg:explorer/license/
    56 sgo:sdDataset articles
    57 rdf:type schema:ScholarlyArticle
    58 N14da0f0de9aa4a40b96e7c592d6c248e rdf:first sg:person.07727214467.39
    59 rdf:rest Nf296114ac96846d9adcdf84dcbf9c7bc
    60 N27826e2392034cfd97a43ef8718937f8 rdf:first sg:person.010452076575.45
    61 rdf:rest N44570ef946764b85a27af06cda145c7a
    62 N44570ef946764b85a27af06cda145c7a rdf:first sg:person.0742761172.43
    63 rdf:rest rdf:nil
    64 N504930961e9249d3a215635af926ece2 schema:name dimensions_id
    65 schema:value pub.1001956182
    66 rdf:type schema:PropertyValue
    67 N5fbcb94bf7984fac96ebcdbcaf4818e5 rdf:first sg:person.0647036243.35
    68 rdf:rest Nfde2ae440e6a4dd7a6c7fb8c2ebf1bf8
    69 N7d3f54f8111b4416b2320eccdcb3a2fa schema:name doi
    70 schema:value 10.1134/s1063774508030048
    71 rdf:type schema:PropertyValue
    72 Nb9f5f264d554403e8b930425d1a7364c schema:name Springer Nature - SN SciGraph project
    73 rdf:type schema:Organization
    74 Nd2476c759cce446aa86b5c44559fada3 rdf:first sg:person.014050706115.26
    75 rdf:rest N27826e2392034cfd97a43ef8718937f8
    76 Nf045cb6c94b74fdf9863695f2ed19126 rdf:first sg:person.01312655701.44
    77 rdf:rest N5fbcb94bf7984fac96ebcdbcaf4818e5
    78 Nf296114ac96846d9adcdf84dcbf9c7bc rdf:first sg:person.012037735004.20
    79 rdf:rest Nd2476c759cce446aa86b5c44559fada3
    80 Nf390c7e9d39e4582bc8d95db78753967 schema:issueNumber 3
    81 rdf:type schema:PublicationIssue
    82 Nf8c9213f98ed4fc498a435a4117bde50 schema:volumeNumber 53
    83 rdf:type schema:PublicationVolume
    84 Nfde2ae440e6a4dd7a6c7fb8c2ebf1bf8 rdf:first sg:person.01327015542.12
    85 rdf:rest N14da0f0de9aa4a40b96e7c592d6c248e
    86 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    87 schema:name Chemical Sciences
    88 rdf:type schema:DefinedTerm
    89 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    90 schema:name Physical Chemistry (incl. Structural)
    91 rdf:type schema:DefinedTerm
    92 sg:journal.1295066 schema:issn 0023-4761
    93 0038-5638
    94 schema:name Crystallography Reports
    95 schema:publisher Pleiades Publishing
    96 rdf:type schema:Periodical
    97 sg:person.010452076575.45 schema:affiliation grid-institutes:grid.4886.2
    98 schema:familyName Konstantinova
    99 schema:givenName A. F.
    100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010452076575.45
    101 rdf:type schema:Person
    102 sg:person.012037735004.20 schema:affiliation grid-institutes:grid.14476.30
    103 schema:familyName Ovchinnikova
    104 schema:givenName E. N.
    105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012037735004.20
    106 rdf:type schema:Person
    107 sg:person.01312655701.44 schema:affiliation grid-institutes:grid.5398.7
    108 schema:familyName Rogalev
    109 schema:givenName A.
    110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01312655701.44
    111 rdf:type schema:Person
    112 sg:person.01327015542.12 schema:affiliation grid-institutes:grid.5398.7
    113 schema:familyName Wilhelm
    114 schema:givenName F.
    115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01327015542.12
    116 rdf:type schema:Person
    117 sg:person.014050706115.26 schema:affiliation grid-institutes:grid.4886.2
    118 schema:familyName Soboleva
    119 schema:givenName L. V.
    120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014050706115.26
    121 rdf:type schema:Person
    122 sg:person.0647036243.35 schema:affiliation grid-institutes:grid.5398.7
    123 schema:familyName Goulon
    124 schema:givenName J.
    125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0647036243.35
    126 rdf:type schema:Person
    127 sg:person.0742761172.43 schema:affiliation grid-institutes:grid.4886.2
    128 schema:familyName Dmitrienko
    129 schema:givenName V. E.
    130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0742761172.43
    131 rdf:type schema:Person
    132 sg:person.07727214467.39 schema:affiliation grid-institutes:grid.14476.30
    133 schema:familyName Kozlovskaya
    134 schema:givenName K. A.
    135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07727214467.39
    136 rdf:type schema:Person
    137 sg:pub.10.1007/3-540-44954-x_3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036773883
    138 https://doi.org/10.1007/3-540-44954-x_3
    139 rdf:type schema:CreativeWork
    140 sg:pub.10.1007/s100510050344 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015159057
    141 https://doi.org/10.1007/s100510050344
    142 rdf:type schema:CreativeWork
    143 grid-institutes:grid.14476.30 schema:alternateName Moscow State University, 119992, Leninskie gory, Moscow, Russia
    144 schema:name Moscow State University, 119992, Leninskie gory, Moscow, Russia
    145 rdf:type schema:Organization
    146 grid-institutes:grid.4886.2 schema:alternateName Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, 119333, Moscow, Russia
    147 schema:name Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, 119333, Moscow, Russia
    148 rdf:type schema:Organization
    149 grid-institutes:grid.5398.7 schema:alternateName European Synchrotron Radiation Facility, Grenoble, France
    150 schema:name European Synchrotron Radiation Facility, Grenoble, France
    151 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...