On the Coexistence of Chemically Similar Stable and Metastable Phases in the BeO–MgO–Al2O3–SiO2 System View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-07

AUTHORS

M. A. Mikhailov, S. G. Mamontova, S. Z. Zelentcov, T. V. Demina, O. Yu. Belozerova, L. A. Bogdanova

ABSTRACT

The joint crystallization of the stable phase (a number of solid solutions of chromium-containing beryllian indialite) and metastable phases (crystalline modifications) of the compound with β-quartz structure (Si0.64Al0.28Mg0.21Be0.09)IVO2 ~ Mg1.89Be0.81Al2.52Si5.76O18 admixed with Cr2O3 phases of khmaralite Mg1.21Cr0.01Be0.46Al1.78Si3.38O20 and spinel {(Mg0.95Be0.045Si0.005)IV(Al1.31Cr0.67Mg0.02)VI}O4 is performed using melted chromium–beryllian indialite preliminarily obtained by solid-phase synthesis as a precursor. Simultaneously, the residual X-ray amorphous melt of composition Mg1.83Cr0.01Be1.04Al2.64Si5.57O18 is hardened. Thus, a reconstructive transition from the beryllian indialite melt to a phase with the β-quartz structure is implemented, and the chemical similarity of these compounds is demonstrated. The rate of change in the crystallization isotherm of 2°С/h and increased heat outflow through the highly heat-conducting walls of the Pt–Rh crucible (taper) contribute to this process. More... »

PAGES

756-760

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1027451018040328

DOI

http://dx.doi.org/10.1134/s1027451018040328

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106015289


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