Supramolecular organization of meso-substituted derivatives of tetraphenylporphine in thin films View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-03

AUTHORS

A. V. Kazak, N. V. Usol’tseva, S. G. Yudin, V. V. Volkov

ABSTRACT

Films of meso-substituted derivatives of tetraphenylporphine substituted in the paraor ortho-positions of the phenyl rings with alkoxy groups (-OC4H9 or -OC16H33) and films of their metal complexes are prepared using the Langmuir-Schaefer (LS) method. The effect of the molecular structure on the supramolecular organization of thin films is determined. The films are obtained by transferring layers of the compounds from the surface of the water onto silicon substrates using the Langmuir-Schaefer technique. The structures of the one-component LS films of the investigated compounds are studied by the small-angle X-ray scattering method, and also the lattice periodicities are calculated. The supramolecular organization of the meso-substituted tetraphenylporphine derivatives is modeled and refined by means of the X-ray diffraction method. When Ni or Cu serve as chelating metal, it is found that the macrocycle-macrocycle interaction is so large that it leads to violation of the molecular linearity, i.e., the lateral substituents are folded toward the macrocycle, reducing the area occupied by the structural units. More... »

PAGES

347-350

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s102745101302033x

DOI

http://dx.doi.org/10.1134/s102745101302033x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041151279


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