In-vitro investigation of magnetron-sputtered coatings based on silicon-substituted hydroxyapatite View Full Text


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Article Info

DATE

2011-12-25

AUTHORS

M. A. Surmeneva, R. A. Surmenev, V. F. Pichugin, S. S. Chernousova, M. Epple

ABSTRACT

Silicon-containing calcium phosphate (Si-CaP) coatings on titanium and austenite steel substrates have been prepared by method of high-frequency magnetron sputtering. The powder of silicon-containing hydroxyapatite Ca10(PO4)6 − x(SiO4)x(HO)2 − x (Si-HA), where x = 0.5 obtained using a mechanochemical technique, was used as a target material. The obtained coatings were X-ray amorphous; the elemental composition of the coatings depended on the composition of the target to be sputtered. The coatings were heated in air for 3 hours to the temperature 700°C with the aim of changing their structure. The bioactivity of the coatings was studied using in-vitro tests. The solution of the simulated body fluid (SBF) oversaturated with respect to HA was used as a model medium. The phase elemental composition and morphology of the deposited and annealed Si-CaP coatings before and after submersion into the solution were controlled using the methods of X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDAX), and scanning electron microscopy (SEM). According to the XFA and IR-spectroscopy data, heat treatment in the air yields the formation of an apatite-like phase in the coating. Thermostating of “metal + coating” specimens in the solution of simulated body fluid revealed that all obtained coatings were biologically active, and a calcium phosphate layer was formed on the coating surface during mineralization. The annealed coatings show a higher chemical stability under physiological conditions as compared to amorphous coatings. More... »

PAGES

1202-1207

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http://scigraph.springernature.com/pub.10.1134/s1027451011120135

DOI

http://dx.doi.org/10.1134/s1027451011120135

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