Semiconductor properties of nanocrystalline diamond electrodes View Full Text


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Article Info

DATE

2014-02

AUTHORS

M. D. Krotova, Yu. V. Pleskov, A. A. Khomich, V. G. Ralchenko, D. N. Sovyk, V. A. Kazakov

ABSTRACT

The semiconductor properties of nitrogenated nanocrystalline diamond electrodes and their corrosion transformations caused by electrochemical experiment in indifferent electrolyte (1 M K2SO4) were studied by the electrochemical impedance spectroscopy method. It was shown that after electrochemical measurements a narrow diamond peak at 1335.7 cm−1 appears in the Raman spectrum; formerly the peak was hidden at a background of the intense signal inherent to graphite-like carbon. It was suggested that the corrosion damage caused by the exposure to electrochemical experiment resulted in a decrease of relative amount of nondiamond (graphite-like) carbon in the subsurface layer in the nanocrystalline diamond. By using Mott-Schottky plots, the nanocrystalline diamond was shown having n-type conductance. Within the bounds of the “effective medium” approach, the nanocrystalline diamond’s flat-band potential in aqueous solution and the noncompensated donor apparent concentration were estimated. More... »

PAGES

101-107

References to SciGraph publications

  • 1967. Electrochemistry of Semiconductors in NONE
  • 2010-09. Electrodes of strongly nitrogenated nanocrystalline diamond in RUSSIAN JOURNAL OF ELECTROCHEMISTRY
  • 2008-07. Nanocrystalline nitrogenated diamond: An N-type electrode material in RUSSIAN JOURNAL OF ELECTROCHEMISTRY
  • 2007-07. Electrochemical behavior of nitrogenated nanocrystalline diamond electrodes in RUSSIAN JOURNAL OF ELECTROCHEMISTRY
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    http://scigraph.springernature.com/pub.10.1134/s1023193514020013

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    http://dx.doi.org/10.1134/s1023193514020013

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