Proton mobility in complex [RhL4Cl2]HSO4 · nH2SO4 · mH2O salts (L = Py, γ-picoline) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-05-20

AUTHORS

D. B. Vasil’chenko, S. V. Korenev, I. A. Baidina, V. A. Drebushchak, N. K. Moroz, S. G. Kozlova, A. S. Ulikhin, N. F. Uvarov

ABSTRACT

The method of deposition from solutions was used to synthesize [RhL4Cl2]HSO4 · nH2SO4 · mH2O complex salts (L = Py, γ-picoline), n ≈ 0.5−0.6, m ≈ 5−6. According to the data of X-ray phase analysis, the crystal structure of these salts is formed by layers of cations separated by layers consisting of anions molecules of sulfuric acid and water connected through a system of hydrogen bonds. Calorimetric methods were used to study phase transitions and the range of thermal stability of salts. The method of 1H NMR spectroscopy discovered that protons within the {HSO4− · nH2SO4 · mH2O} subsystem featured enhanced conductivity. Conductivity studies showed that trans-[RhL4Cl2]HSO4 · nH2SO4 · mH2O samples had high proton conductivity. More... »

PAGES

631

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s102319351105017x

DOI

http://dx.doi.org/10.1134/s102319351105017x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027971386


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