Thermal and dielectric characterization of multi-walled carbon nanotubes−thermoplastic polyurethanes composites View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2017-07

AUTHORS

M. J. Sanchis, M. Carsí, C. A. Gracia-Fernández

ABSTRACT

Multi-walled carbon nanotubes–thermoplastic polyurethanes composites were characterized by means of differential scanning calorimetry and dielectric relaxation spectroscopy. The composite is characterized by two glass transition temperatures Tg. The Tg associated with the soft segment decreases by increasing of carbon nanotubes content, while carbon nanotubes content has practically no effect on the value of the Tg associated with the hard segments. It was observed that rising the temperature and carbon nanotubes content resulted in the increased of both the dielectric permittivity and the loss factor. The presence of carbon nanotubes produces an enhancement of charge carriers trapping, increasing the electrical conductivity. The electrical conductivity of the composite was found to exhibit an insulator to conductor transition at a carbon nanotubes critical content, i.e., the percolation threshold, near 6 wt %. More... »

PAGES

543-553

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965545x17040083

DOI

http://dx.doi.org/10.1134/s0965545x17040083

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090884683


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