Orientational processes in the yarns of high-molecular-mass cellulose acetate in vapors of nitromethane and its mixture with water View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-02

AUTHORS

A. B. Shipovskaya, G. N. Timofeeva, A. Yu. Abramov, S. Yu. Shchegolev, V. P. Ryabukho

ABSTRACT

The phenomenon of spontaneous changes in the linear dimensions (elongation-contraction) is described for commercial and laboratory samples of acetate yarns processed by wet spinning from high- molecular -mass cellulose diacetate in vapors of a mesophas ogenic solvent (which is able to form a lyotropic LC phase with the polymer), nitromethane, and its mixtures with water. The thermodeformational, elastic- plastic, physicomechanical, and surface characteristics of the yarns at different stages of their spontaneous deformation are analyzed. When samples are treated with probe vapors, orientational processes in the polymer matrix are activated, and this observation makes it possible to prepare yarns with improved physicomechanical characteristics and with low linear density. A new phenomenon (to our knowledge) of cyclic three- stage deformation of acetate monofilaments in nitromethane vapors is discovered. This evidence is interpreted from the standpoint of phase (amorphous glassy-liquid crystalline state) and conformational transitions as well as by the mechanism of interaction between polymers and solvent vapors and related development of the LC phase. More... »

PAGES

126-133

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965545x10020033

DOI

http://dx.doi.org/10.1134/s0965545x10020033

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048452949


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Saratov State University", 
          "id": "https://www.grid.ac/institutes/grid.446088.6", 
          "name": [
            "Chernyshevsky Saratov State University, ul. Astrahanskaya 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shipovskaya", 
        "givenName": "A. B.", 
        "id": "sg:person.016474137722.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016474137722.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Saratov State University", 
          "id": "https://www.grid.ac/institutes/grid.446088.6", 
          "name": [
            "Research Institute of Natural Sciences, Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Timofeeva", 
        "givenName": "G. N.", 
        "id": "sg:person.015472312677.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015472312677.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Saratov State University", 
          "id": "https://www.grid.ac/institutes/grid.446088.6", 
          "name": [
            "Chernyshevsky Saratov State University, ul. Astrahanskaya 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Abramov", 
        "givenName": "A. Yu.", 
        "id": "sg:person.014731653143.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014731653143.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Chernyshevsky Saratov State University, ul. Astrahanskaya 83, 410012, Saratov, Russia", 
            "Institute of Biochemistry and Physiology of Microorganisms, Russian Academy of Sciences, pr. Entuziastov 13, 410049, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shchegolev", 
        "givenName": "S. Yu.", 
        "id": "sg:person.011562116471.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011562116471.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Saratov State University", 
          "id": "https://www.grid.ac/institutes/grid.446088.6", 
          "name": [
            "Chernyshevsky Saratov State University, ul. Astrahanskaya 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ryabukho", 
        "givenName": "V. P.", 
        "id": "sg:person.014133731031.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014133731031.38"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0965545x07110089", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007753182", 
          "https://doi.org/10.1134/s0965545x07110089"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965545x06050087", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007852565", 
          "https://doi.org/10.1134/s0965545x06050087"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1098/rspa.1956.0016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011774787"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/01406568008070497", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012822532"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1964.110020122", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049203302"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/polc.5070380111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050062721"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/polc.5070380111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050062721"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1077227919", 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-02", 
    "datePublishedReg": "2010-02-01", 
    "description": "The phenomenon of spontaneous changes in the linear dimensions (elongation-contraction) is described for commercial and laboratory samples of acetate yarns processed by wet spinning from high- molecular -mass cellulose diacetate in vapors of a mesophas ogenic solvent (which is able to form a lyotropic LC phase with the polymer), nitromethane, and its mixtures with water. The thermodeformational, elastic- plastic, physicomechanical, and surface characteristics of the yarns at different stages of their spontaneous deformation are analyzed. When samples are treated with probe vapors, orientational processes in the polymer matrix are activated, and this observation makes it possible to prepare yarns with improved physicomechanical characteristics and with low linear density. A new phenomenon (to our knowledge) of cyclic three- stage deformation of acetate monofilaments in nitromethane vapors is discovered. This evidence is interpreted from the standpoint of phase (amorphous glassy-liquid crystalline state) and conformational transitions as well as by the mechanism of interaction between polymers and solvent vapors and related development of the LC phase.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0965545x10020033", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1043515", 
        "issn": [
          "1757-1820", 
          "1555-6107"
        ], 
        "name": "Polymer Science, Series A", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "52"
      }
    ], 
    "name": "Orientational processes in the yarns of high-molecular-mass cellulose acetate in vapors of nitromethane and its mixture with water", 
    "pagination": "126-133", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e6d233d53c2bf70b28b95b21884fe73ca4d4af501a12a92af19b0d8dfcf7aae0"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965545x10020033"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1048452949"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965545x10020033", 
      "https://app.dimensions.ai/details/publication/pub.1048452949"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:56", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000347_0000000347/records_89804_00000002.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0965545X10020033"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965545x10020033'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965545x10020033'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965545x10020033'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965545x10020033'


 

This table displays all metadata directly associated to this object as RDF triples.

116 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965545x10020033 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Ne12956c92555497bbc15ddb02c0d7f39
4 schema:citation sg:pub.10.1134/s0965545x06050087
5 sg:pub.10.1134/s0965545x07110089
6 https://app.dimensions.ai/details/publication/pub.1077227919
7 https://doi.org/10.1002/pol.1964.110020122
8 https://doi.org/10.1002/polc.5070380111
9 https://doi.org/10.1080/01406568008070497
10 https://doi.org/10.1098/rspa.1956.0016
11 schema:datePublished 2010-02
12 schema:datePublishedReg 2010-02-01
13 schema:description The phenomenon of spontaneous changes in the linear dimensions (elongation-contraction) is described for commercial and laboratory samples of acetate yarns processed by wet spinning from high- molecular -mass cellulose diacetate in vapors of a mesophas ogenic solvent (which is able to form a lyotropic LC phase with the polymer), nitromethane, and its mixtures with water. The thermodeformational, elastic- plastic, physicomechanical, and surface characteristics of the yarns at different stages of their spontaneous deformation are analyzed. When samples are treated with probe vapors, orientational processes in the polymer matrix are activated, and this observation makes it possible to prepare yarns with improved physicomechanical characteristics and with low linear density. A new phenomenon (to our knowledge) of cyclic three- stage deformation of acetate monofilaments in nitromethane vapors is discovered. This evidence is interpreted from the standpoint of phase (amorphous glassy-liquid crystalline state) and conformational transitions as well as by the mechanism of interaction between polymers and solvent vapors and related development of the LC phase.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N72400f2c9058448ba64b8069a2e9429f
18 Nea92845c266946f5ad576c79268e0789
19 sg:journal.1043515
20 schema:name Orientational processes in the yarns of high-molecular-mass cellulose acetate in vapors of nitromethane and its mixture with water
21 schema:pagination 126-133
22 schema:productId N0fb8d6fba6994c20a72752a86124b532
23 N6533a0b4767a46a1ac0e598506bc8013
24 Nbbbad91b80094f3d90828281b23ba400
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048452949
26 https://doi.org/10.1134/s0965545x10020033
27 schema:sdDatePublished 2019-04-11T09:56
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher N071d3f5fabf24c008162c31de8ceb1d1
30 schema:url http://link.springer.com/10.1134/S0965545X10020033
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N071d3f5fabf24c008162c31de8ceb1d1 schema:name Springer Nature - SN SciGraph project
35 rdf:type schema:Organization
36 N07f59db0bf5b4dae9ea2499ae3bbd56b rdf:first sg:person.014731653143.06
37 rdf:rest N3abd0939eaa94d42ae95e6af2ab38dd7
38 N0fb8d6fba6994c20a72752a86124b532 schema:name doi
39 schema:value 10.1134/s0965545x10020033
40 rdf:type schema:PropertyValue
41 N3abd0939eaa94d42ae95e6af2ab38dd7 rdf:first sg:person.011562116471.77
42 rdf:rest N9d9a4eb07cc14626a205d146b1f2406f
43 N6533a0b4767a46a1ac0e598506bc8013 schema:name readcube_id
44 schema:value e6d233d53c2bf70b28b95b21884fe73ca4d4af501a12a92af19b0d8dfcf7aae0
45 rdf:type schema:PropertyValue
46 N72400f2c9058448ba64b8069a2e9429f schema:volumeNumber 52
47 rdf:type schema:PublicationVolume
48 N9d9a4eb07cc14626a205d146b1f2406f rdf:first sg:person.014133731031.38
49 rdf:rest rdf:nil
50 Nbbbad91b80094f3d90828281b23ba400 schema:name dimensions_id
51 schema:value pub.1048452949
52 rdf:type schema:PropertyValue
53 Ne013a6c6dc8347669c19dd31a9aa9b83 rdf:first sg:person.015472312677.79
54 rdf:rest N07f59db0bf5b4dae9ea2499ae3bbd56b
55 Ne12956c92555497bbc15ddb02c0d7f39 rdf:first sg:person.016474137722.10
56 rdf:rest Ne013a6c6dc8347669c19dd31a9aa9b83
57 Nea92845c266946f5ad576c79268e0789 schema:issueNumber 2
58 rdf:type schema:PublicationIssue
59 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
60 schema:name Chemical Sciences
61 rdf:type schema:DefinedTerm
62 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
63 schema:name Macromolecular and Materials Chemistry
64 rdf:type schema:DefinedTerm
65 sg:journal.1043515 schema:issn 1555-6107
66 1757-1820
67 schema:name Polymer Science, Series A
68 rdf:type schema:Periodical
69 sg:person.011562116471.77 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
70 schema:familyName Shchegolev
71 schema:givenName S. Yu.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011562116471.77
73 rdf:type schema:Person
74 sg:person.014133731031.38 schema:affiliation https://www.grid.ac/institutes/grid.446088.6
75 schema:familyName Ryabukho
76 schema:givenName V. P.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014133731031.38
78 rdf:type schema:Person
79 sg:person.014731653143.06 schema:affiliation https://www.grid.ac/institutes/grid.446088.6
80 schema:familyName Abramov
81 schema:givenName A. Yu.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014731653143.06
83 rdf:type schema:Person
84 sg:person.015472312677.79 schema:affiliation https://www.grid.ac/institutes/grid.446088.6
85 schema:familyName Timofeeva
86 schema:givenName G. N.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015472312677.79
88 rdf:type schema:Person
89 sg:person.016474137722.10 schema:affiliation https://www.grid.ac/institutes/grid.446088.6
90 schema:familyName Shipovskaya
91 schema:givenName A. B.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016474137722.10
93 rdf:type schema:Person
94 sg:pub.10.1134/s0965545x06050087 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007852565
95 https://doi.org/10.1134/s0965545x06050087
96 rdf:type schema:CreativeWork
97 sg:pub.10.1134/s0965545x07110089 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007753182
98 https://doi.org/10.1134/s0965545x07110089
99 rdf:type schema:CreativeWork
100 https://app.dimensions.ai/details/publication/pub.1077227919 schema:CreativeWork
101 https://doi.org/10.1002/pol.1964.110020122 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049203302
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1002/polc.5070380111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050062721
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1080/01406568008070497 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012822532
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1098/rspa.1956.0016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011774787
108 rdf:type schema:CreativeWork
109 https://www.grid.ac/institutes/grid.446088.6 schema:alternateName Saratov State University
110 schema:name Chernyshevsky Saratov State University, ul. Astrahanskaya 83, 410012, Saratov, Russia
111 Research Institute of Natural Sciences, Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia
112 rdf:type schema:Organization
113 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
114 schema:name Chernyshevsky Saratov State University, ul. Astrahanskaya 83, 410012, Saratov, Russia
115 Institute of Biochemistry and Physiology of Microorganisms, Russian Academy of Sciences, pr. Entuziastov 13, 410049, Saratov, Russia
116 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...