Optical-activity anisotropy of ordered phases in cellulose acetates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-07

AUTHORS

A. B. Shipovskaya, S. L. Shmakov, O. F. Kazmicheva, S. Yu. Shchegolev

ABSTRACT

The optical activity of anisotropic solutions of cellulose diacetate in nitromethane and dimethyl sulfoxide and of diand triacetate films with vitrified ordered structure has been studied. The systems under study are characterized by high specific optical rotation [α], suggesting formation of a cholesteric mesophase. The value of [α] is found to depend on the angle of rotation of the samples relative to the direction of the polarization vector of an incident light beam in the plane perpendicular to this beam (the anisotropy of optical activity). This dependence (indicatrix) shows an irregular pattern and, when plotted in Cartesian coordinates, can be described with a distorted sinusoid. The data on the resolution of indicatrices into harmonic constituents and isolation of contributions due to isotropic components and anisotropic components, each of which is determined by the structural element with the corresponding asymmetry, are analyzed. More... »

PAGES

773-784

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965545x09070049

DOI

http://dx.doi.org/10.1134/s0965545x09070049

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009228315


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shipovskaya", 
        "givenName": "A. B.", 
        "id": "sg:person.016474137722.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016474137722.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shmakov", 
        "givenName": "S. L.", 
        "id": "sg:person.01105560522.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01105560522.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kazmicheva", 
        "givenName": "O. F.", 
        "id": "sg:person.013061553501.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013061553501.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Biochemistry and Physiology of Plants and Microorganisms", 
          "id": "https://www.grid.ac/institutes/grid.465333.4", 
          "name": [
            "Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia", 
            "Institute of Biochemistry and Physiology of Plants and Microorganisms, Russian Academy of Sciences, pr. Entuziastov 13, 410049, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shchegolev", 
        "givenName": "S. Yu.", 
        "id": "sg:person.011562116471.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011562116471.77"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/15421407608083894", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002284533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/apmc.1989.051660109", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005557291"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965545x07110089", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007753182", 
          "https://doi.org/10.1134/s0965545x07110089"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965545x06050087", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007852565", 
          "https://doi.org/10.1134/s0965545x06050087"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1098/rspa.1956.0016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011774787"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/01406568008070497", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012822532"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/bip.360270904", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023122332"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1980.180180401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029024238"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(82)90113-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048723756"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(82)90113-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048723756"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1964.110020122", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049203302"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/bip.360271210", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050041866"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pen.760150311", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052321154"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma50004a049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056198165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.76.529", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064477131"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1077227919", 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2009-07", 
    "datePublishedReg": "2009-07-01", 
    "description": "The optical activity of anisotropic solutions of cellulose diacetate in nitromethane and dimethyl sulfoxide and of diand triacetate films with vitrified ordered structure has been studied. The systems under study are characterized by high specific optical rotation [\u03b1], suggesting formation of a cholesteric mesophase. The value of [\u03b1] is found to depend on the angle of rotation of the samples relative to the direction of the polarization vector of an incident light beam in the plane perpendicular to this beam (the anisotropy of optical activity). This dependence (indicatrix) shows an irregular pattern and, when plotted in Cartesian coordinates, can be described with a distorted sinusoid. The data on the resolution of indicatrices into harmonic constituents and isolation of contributions due to isotropic components and anisotropic components, each of which is determined by the structural element with the corresponding asymmetry, are analyzed.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0965545x09070049", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1043515", 
        "issn": [
          "1757-1820", 
          "1555-6107"
        ], 
        "name": "Polymer Science, Series A", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "name": "Optical-activity anisotropy of ordered phases in cellulose acetates", 
    "pagination": "773-784", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "2bf61bebba32ed782898fc14ea25a36a60fe8d6ce1a01e11134b3e02e4a12229"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965545x09070049"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1009228315"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965545x09070049", 
      "https://app.dimensions.ai/details/publication/pub.1009228315"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:25", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000345_0000000345/records_64106_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0965545X09070049"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965545x09070049'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965545x09070049'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965545x09070049'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965545x09070049'


 

This table displays all metadata directly associated to this object as RDF triples.

135 TRIPLES      21 PREDICATES      42 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965545x09070049 schema:about anzsrc-for:02
2 anzsrc-for:0299
3 schema:author N75bfb2a782524b2fbaffcb2d63ecad69
4 schema:citation sg:pub.10.1134/s0965545x06050087
5 sg:pub.10.1134/s0965545x07110089
6 https://app.dimensions.ai/details/publication/pub.1077227919
7 https://doi.org/10.1002/apmc.1989.051660109
8 https://doi.org/10.1002/bip.360270904
9 https://doi.org/10.1002/bip.360271210
10 https://doi.org/10.1002/pen.760150311
11 https://doi.org/10.1002/pol.1964.110020122
12 https://doi.org/10.1002/pol.1980.180180401
13 https://doi.org/10.1016/0032-3861(82)90113-6
14 https://doi.org/10.1021/ma50004a049
15 https://doi.org/10.1080/01406568008070497
16 https://doi.org/10.1080/15421407608083894
17 https://doi.org/10.1098/rspa.1956.0016
18 https://doi.org/10.1246/bcsj.76.529
19 schema:datePublished 2009-07
20 schema:datePublishedReg 2009-07-01
21 schema:description The optical activity of anisotropic solutions of cellulose diacetate in nitromethane and dimethyl sulfoxide and of diand triacetate films with vitrified ordered structure has been studied. The systems under study are characterized by high specific optical rotation [α], suggesting formation of a cholesteric mesophase. The value of [α] is found to depend on the angle of rotation of the samples relative to the direction of the polarization vector of an incident light beam in the plane perpendicular to this beam (the anisotropy of optical activity). This dependence (indicatrix) shows an irregular pattern and, when plotted in Cartesian coordinates, can be described with a distorted sinusoid. The data on the resolution of indicatrices into harmonic constituents and isolation of contributions due to isotropic components and anisotropic components, each of which is determined by the structural element with the corresponding asymmetry, are analyzed.
22 schema:genre research_article
23 schema:inLanguage en
24 schema:isAccessibleForFree false
25 schema:isPartOf Ncc0d9d97fd1543c0aff180f2bdbd25e2
26 Ndaac52f36f704ad298d78adcd497dba9
27 sg:journal.1043515
28 schema:name Optical-activity anisotropy of ordered phases in cellulose acetates
29 schema:pagination 773-784
30 schema:productId Nbf4df8a6a8ac43009f03db1baaf23f12
31 Ne03b97732cdb493da4f6f3202412742c
32 Nf1337fd4f0b44a349dee63048e3361bf
33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009228315
34 https://doi.org/10.1134/s0965545x09070049
35 schema:sdDatePublished 2019-04-11T09:25
36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
37 schema:sdPublisher Nfe19d815bf5049459562961faab26d04
38 schema:url http://link.springer.com/10.1134/S0965545X09070049
39 sgo:license sg:explorer/license/
40 sgo:sdDataset articles
41 rdf:type schema:ScholarlyArticle
42 N01e372775cac4d8a83bc634d917bbfea rdf:first sg:person.013061553501.94
43 rdf:rest Nf60acd3cce004376967a6a9cf8d3d309
44 N1a56186a1e224f75bf3f5a3411ee6407 rdf:first sg:person.01105560522.18
45 rdf:rest N01e372775cac4d8a83bc634d917bbfea
46 N4a5be5d7d10c4a458eada956f83307c4 schema:name Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia
47 rdf:type schema:Organization
48 N5c31b8ef37304682b4db3be34f5c25f0 schema:name Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia
49 rdf:type schema:Organization
50 N75bfb2a782524b2fbaffcb2d63ecad69 rdf:first sg:person.016474137722.10
51 rdf:rest N1a56186a1e224f75bf3f5a3411ee6407
52 N77c581493898406eb44e17b8a6aab129 schema:name Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia
53 rdf:type schema:Organization
54 Nbf4df8a6a8ac43009f03db1baaf23f12 schema:name doi
55 schema:value 10.1134/s0965545x09070049
56 rdf:type schema:PropertyValue
57 Ncc0d9d97fd1543c0aff180f2bdbd25e2 schema:issueNumber 7
58 rdf:type schema:PublicationIssue
59 Ndaac52f36f704ad298d78adcd497dba9 schema:volumeNumber 51
60 rdf:type schema:PublicationVolume
61 Ne03b97732cdb493da4f6f3202412742c schema:name readcube_id
62 schema:value 2bf61bebba32ed782898fc14ea25a36a60fe8d6ce1a01e11134b3e02e4a12229
63 rdf:type schema:PropertyValue
64 Nf1337fd4f0b44a349dee63048e3361bf schema:name dimensions_id
65 schema:value pub.1009228315
66 rdf:type schema:PropertyValue
67 Nf60acd3cce004376967a6a9cf8d3d309 rdf:first sg:person.011562116471.77
68 rdf:rest rdf:nil
69 Nfe19d815bf5049459562961faab26d04 schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
72 schema:name Physical Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0299 schema:inDefinedTermSet anzsrc-for:
75 schema:name Other Physical Sciences
76 rdf:type schema:DefinedTerm
77 sg:journal.1043515 schema:issn 1555-6107
78 1757-1820
79 schema:name Polymer Science, Series A
80 rdf:type schema:Periodical
81 sg:person.01105560522.18 schema:affiliation N5c31b8ef37304682b4db3be34f5c25f0
82 schema:familyName Shmakov
83 schema:givenName S. L.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01105560522.18
85 rdf:type schema:Person
86 sg:person.011562116471.77 schema:affiliation https://www.grid.ac/institutes/grid.465333.4
87 schema:familyName Shchegolev
88 schema:givenName S. Yu.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011562116471.77
90 rdf:type schema:Person
91 sg:person.013061553501.94 schema:affiliation N4a5be5d7d10c4a458eada956f83307c4
92 schema:familyName Kazmicheva
93 schema:givenName O. F.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013061553501.94
95 rdf:type schema:Person
96 sg:person.016474137722.10 schema:affiliation N77c581493898406eb44e17b8a6aab129
97 schema:familyName Shipovskaya
98 schema:givenName A. B.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016474137722.10
100 rdf:type schema:Person
101 sg:pub.10.1134/s0965545x06050087 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007852565
102 https://doi.org/10.1134/s0965545x06050087
103 rdf:type schema:CreativeWork
104 sg:pub.10.1134/s0965545x07110089 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007753182
105 https://doi.org/10.1134/s0965545x07110089
106 rdf:type schema:CreativeWork
107 https://app.dimensions.ai/details/publication/pub.1077227919 schema:CreativeWork
108 https://doi.org/10.1002/apmc.1989.051660109 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005557291
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1002/bip.360270904 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023122332
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1002/bip.360271210 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050041866
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1002/pen.760150311 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052321154
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1002/pol.1964.110020122 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049203302
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1002/pol.1980.180180401 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029024238
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/0032-3861(82)90113-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048723756
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1021/ma50004a049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056198165
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1080/01406568008070497 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012822532
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1080/15421407608083894 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002284533
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1098/rspa.1956.0016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011774787
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1246/bcsj.76.529 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064477131
131 rdf:type schema:CreativeWork
132 https://www.grid.ac/institutes/grid.465333.4 schema:alternateName Institute of Biochemistry and Physiology of Plants and Microorganisms
133 schema:name Chernyshevskii State University, Astrakhanskaya ul. 83, 410012, Saratov, Russia
134 Institute of Biochemistry and Physiology of Plants and Microorganisms, Russian Academy of Sciences, pr. Entuziastov 13, 410049, Saratov, Russia
135 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...