Epoxy oligomers based on eugenol cyclotriphosphazene derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-06

AUTHORS

V. V. Kireev, N. S. Bredov, Yu. V. Bilichenko, K. A. Lysenko, R. S. Borisov, V. P. Chuev

ABSTRACT

Oligomers of hexakis(4-allyl-2-methoxyphenoxy)cyclotriphosphazene have been synthesized and their molecular structure studied by X-ray and NMR analysis. The nonplanar character of a phosphazene cycle is established, and the bond lengths P-N and valence angles N-P-N are shown to change in narrow ranges (1.5771–1.5894 Å and 117.80°–118.37°, respectively). During epoxidation of hexakis(4-allyl-2-methoxyphenoxy)cyclotriphosphazene by m-chloroperbenzoic acid or peracetic acid, in addition to hexaepoxy derivatives, the corresponding dimer is formed due to partial intermolecular interaction of epoxy groups. More... »

PAGES

609-615

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965545x08060035

DOI

http://dx.doi.org/10.1134/s0965545x08060035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029276023


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