Degradation of poly(terphenylenephthalide) at high temperatures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12

AUTHORS

V. A. Kraikin, Z. N. Musina, E. G. Galkin, S. I. Kuznetsov, A. E. Egorov, S. N. Salazkin

ABSTRACT

The thermal and thermooxidative degradation of poly(terphenylenephthalide) has been studied by thermal analysis, IR and UV spectroscopy, and mass spectrometry. On the basis of the spectral data and the chemical composition of degradation products, it has been shown that both the thermal and thermooxidative degradations of poly(terphenylenephthalide) are characterized by intramolecular cyclization reactions. Depending on the mode of closure of intermediates generated in the course of thermal decomposition of neighboring phthalide groups (head-to-head or head-to-tail), either phenyl-substituted anthraquinones, fluorenones, and fluorenes or symmetric and nonsymmetric dicyclic compounds containing end anthraquinone, fluorenone, and fluorene groups may be formed. The oxidation of poly(terphenylenephthalide) likewise gives rise to cyclic products—the compounds of xanthone and dibenzofuran series. More... »

PAGES

1287-1303

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965545x06120108

DOI

http://dx.doi.org/10.1134/s0965545x06120108

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034964940


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kraikin", 
        "givenName": "V. A.", 
        "id": "sg:person.01116000665.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01116000665.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Musina", 
        "givenName": "Z. N.", 
        "id": "sg:person.012550337640.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012550337640.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Galkin", 
        "givenName": "E. G.", 
        "id": "sg:person.016237031515.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016237031515.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kuznetsov", 
        "givenName": "S. I.", 
        "id": "sg:person.014540625545.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014540625545.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Egorov", 
        "givenName": "A. E.", 
        "id": "sg:person.01346455665.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01346455665.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Salazkin", 
        "givenName": "S. N.", 
        "id": "sg:person.0623051565.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0623051565.31"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2006-12", 
    "datePublishedReg": "2006-12-01", 
    "description": "The thermal and thermooxidative degradation of poly(terphenylenephthalide) has been studied by thermal analysis, IR and UV spectroscopy, and mass spectrometry. On the basis of the spectral data and the chemical composition of degradation products, it has been shown that both the thermal and thermooxidative degradations of poly(terphenylenephthalide) are characterized by intramolecular cyclization reactions. Depending on the mode of closure of intermediates generated in the course of thermal decomposition of neighboring phthalide groups (head-to-head or head-to-tail), either phenyl-substituted anthraquinones, fluorenones, and fluorenes or symmetric and nonsymmetric dicyclic compounds containing end anthraquinone, fluorenone, and fluorene groups may be formed. The oxidation of poly(terphenylenephthalide) likewise gives rise to cyclic products\u2014the compounds of xanthone and dibenzofuran series.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0965545x06120108", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1043515", 
        "issn": [
          "1757-1820", 
          "1555-6107"
        ], 
        "name": "Polymer Science Series A", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "keywords": [
      "thermooxidative degradation", 
      "intramolecular cyclization reaction", 
      "fluorene groups", 
      "phthalide groups", 
      "cyclic products", 
      "UV spectroscopy", 
      "cyclization reaction", 
      "dibenzofuran series", 
      "thermal decomposition", 
      "mass spectrometry", 
      "thermal analysis", 
      "degradation products", 
      "chemical composition", 
      "spectral data", 
      "fluorenone", 
      "compounds", 
      "anthraquinones", 
      "high temperature", 
      "spectroscopy", 
      "IR", 
      "degradation", 
      "fluorene", 
      "spectrometry", 
      "oxidation", 
      "products", 
      "intermediates", 
      "reaction", 
      "mode of closure", 
      "xanthones", 
      "decomposition", 
      "composition", 
      "temperature", 
      "series", 
      "group", 
      "mode", 
      "analysis", 
      "basis", 
      "data", 
      "closure", 
      "course", 
      "phenyl-substituted anthraquinones", 
      "nonsymmetric dicyclic compounds", 
      "dicyclic compounds", 
      "end anthraquinone", 
      "compounds of xanthone"
    ], 
    "name": "Degradation of poly(terphenylenephthalide) at high temperatures", 
    "pagination": "1287-1303", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1034964940"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965545x06120108"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965545x06120108", 
      "https://app.dimensions.ai/details/publication/pub.1034964940"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:09", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_423.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0965545x06120108"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965545x06120108'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965545x06120108'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965545x06120108'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965545x06120108'


 

This table displays all metadata directly associated to this object as RDF triples.

141 TRIPLES      21 PREDICATES      71 URIs      63 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965545x06120108 schema:about anzsrc-for:03
2 anzsrc-for:0399
3 schema:author N5b78576b19f84cfa92fbc34166b2c775
4 schema:datePublished 2006-12
5 schema:datePublishedReg 2006-12-01
6 schema:description The thermal and thermooxidative degradation of poly(terphenylenephthalide) has been studied by thermal analysis, IR and UV spectroscopy, and mass spectrometry. On the basis of the spectral data and the chemical composition of degradation products, it has been shown that both the thermal and thermooxidative degradations of poly(terphenylenephthalide) are characterized by intramolecular cyclization reactions. Depending on the mode of closure of intermediates generated in the course of thermal decomposition of neighboring phthalide groups (head-to-head or head-to-tail), either phenyl-substituted anthraquinones, fluorenones, and fluorenes or symmetric and nonsymmetric dicyclic compounds containing end anthraquinone, fluorenone, and fluorene groups may be formed. The oxidation of poly(terphenylenephthalide) likewise gives rise to cyclic products—the compounds of xanthone and dibenzofuran series.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N91c277f9d50b44f0ae65c8b82015840f
11 Nea4d237dc9374114b528e37764f58baa
12 sg:journal.1043515
13 schema:keywords IR
14 UV spectroscopy
15 analysis
16 anthraquinones
17 basis
18 chemical composition
19 closure
20 composition
21 compounds
22 compounds of xanthone
23 course
24 cyclic products
25 cyclization reaction
26 data
27 decomposition
28 degradation
29 degradation products
30 dibenzofuran series
31 dicyclic compounds
32 end anthraquinone
33 fluorene
34 fluorene groups
35 fluorenone
36 group
37 high temperature
38 intermediates
39 intramolecular cyclization reaction
40 mass spectrometry
41 mode
42 mode of closure
43 nonsymmetric dicyclic compounds
44 oxidation
45 phenyl-substituted anthraquinones
46 phthalide groups
47 products
48 reaction
49 series
50 spectral data
51 spectrometry
52 spectroscopy
53 temperature
54 thermal analysis
55 thermal decomposition
56 thermooxidative degradation
57 xanthones
58 schema:name Degradation of poly(terphenylenephthalide) at high temperatures
59 schema:pagination 1287-1303
60 schema:productId N6b88109463e443f0b14ab478a6b264ec
61 Na485832e9248454aac249cbe4755d75b
62 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034964940
63 https://doi.org/10.1134/s0965545x06120108
64 schema:sdDatePublished 2021-11-01T18:09
65 schema:sdLicense https://scigraph.springernature.com/explorer/license/
66 schema:sdPublisher N0e88d0f5f1384006968ed6186764dd65
67 schema:url https://doi.org/10.1134/s0965545x06120108
68 sgo:license sg:explorer/license/
69 sgo:sdDataset articles
70 rdf:type schema:ScholarlyArticle
71 N06f7f1a59b1a472a8b1a765f933a3ef7 rdf:first sg:person.016237031515.10
72 rdf:rest Nd51d93166a284f53a1d7189c972eff0a
73 N0e88d0f5f1384006968ed6186764dd65 schema:name Springer Nature - SN SciGraph project
74 rdf:type schema:Organization
75 N240ff151783c4470a2efbb8f7ebe4185 rdf:first sg:person.0623051565.31
76 rdf:rest rdf:nil
77 N5b78576b19f84cfa92fbc34166b2c775 rdf:first sg:person.01116000665.01
78 rdf:rest N5da51970e6a347f3a9c34d1967e911bd
79 N5da51970e6a347f3a9c34d1967e911bd rdf:first sg:person.012550337640.04
80 rdf:rest N06f7f1a59b1a472a8b1a765f933a3ef7
81 N6b88109463e443f0b14ab478a6b264ec schema:name doi
82 schema:value 10.1134/s0965545x06120108
83 rdf:type schema:PropertyValue
84 N91c277f9d50b44f0ae65c8b82015840f schema:volumeNumber 48
85 rdf:type schema:PublicationVolume
86 Na485832e9248454aac249cbe4755d75b schema:name dimensions_id
87 schema:value pub.1034964940
88 rdf:type schema:PropertyValue
89 Nd51d93166a284f53a1d7189c972eff0a rdf:first sg:person.014540625545.71
90 rdf:rest Ne455e736d4304e41a2e89f774552b6f8
91 Ne455e736d4304e41a2e89f774552b6f8 rdf:first sg:person.01346455665.54
92 rdf:rest N240ff151783c4470a2efbb8f7ebe4185
93 Nea4d237dc9374114b528e37764f58baa schema:issueNumber 12
94 rdf:type schema:PublicationIssue
95 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
96 schema:name Chemical Sciences
97 rdf:type schema:DefinedTerm
98 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
99 schema:name Other Chemical Sciences
100 rdf:type schema:DefinedTerm
101 sg:journal.1043515 schema:issn 1555-6107
102 1757-1820
103 schema:name Polymer Science Series A
104 schema:publisher Pleiades Publishing
105 rdf:type schema:Periodical
106 sg:person.01116000665.01 schema:affiliation grid-institutes:grid.4886.2
107 schema:familyName Kraikin
108 schema:givenName V. A.
109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01116000665.01
110 rdf:type schema:Person
111 sg:person.012550337640.04 schema:affiliation grid-institutes:grid.4886.2
112 schema:familyName Musina
113 schema:givenName Z. N.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012550337640.04
115 rdf:type schema:Person
116 sg:person.01346455665.54 schema:affiliation grid-institutes:grid.4886.2
117 schema:familyName Egorov
118 schema:givenName A. E.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01346455665.54
120 rdf:type schema:Person
121 sg:person.014540625545.71 schema:affiliation grid-institutes:grid.4886.2
122 schema:familyName Kuznetsov
123 schema:givenName S. I.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014540625545.71
125 rdf:type schema:Person
126 sg:person.016237031515.10 schema:affiliation grid-institutes:grid.4886.2
127 schema:familyName Galkin
128 schema:givenName E. G.
129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016237031515.10
130 rdf:type schema:Person
131 sg:person.0623051565.31 schema:affiliation grid-institutes:grid.431939.5
132 schema:familyName Salazkin
133 schema:givenName S. N.
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0623051565.31
135 rdf:type schema:Person
136 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
137 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
138 rdf:type schema:Organization
139 grid-institutes:grid.4886.2 schema:alternateName Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia
140 schema:name Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, pr. Oktyabrya 71, 450054, Ufa, Bashkortostan, Russia
141 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...