Preparation of Purified Hydrogen by Selective Hydrogenation of Carbon Monoxide in a Mixture of Steam Reforming Products of Organic Substrates ... View Full Text


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Article Info

DATE

2018-12

AUTHORS

A. S. Fedotov, D. O. Antonov, S. S. Kurdyumov, G. I. Konstantinov, V. I. Uvarov, M. V. Tsodikov

ABSTRACT

The scientific basis has been developed for the production of purified hydrogen via the hydrogenation of CO formed by the steam reforming of fermentation products in a porous Ni(Al)–Co converter made by self-propagating high-temperature synthesis. It has been shown that the rate of CO hydrogenation in catalytic channels of the converter is higher by a factor of 3–3.5 than the rate achieved in a flow reactor with a fixed bed of a granular catalyst of the same composition. If the steam reforming processes with an H2O/organic substrate ratio of ~15–20 are self-consistent with the subsequent hydrogenation of carbon monoxide by the “intrinsic” hydrogen, the carbon monoxide conversion per pass at 300°C is 97.5% with a residual CO content in the gas of ≤0.1%. The approach considered in the paper is promising for producing hydrogen as a fuel for medium-temperature fuel cells. More... »

PAGES

1019-1022

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544118120022

DOI

http://dx.doi.org/10.1134/s0965544118120022

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110564751


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