Quantum-Chemical and Experimental Investigation of the Catalytic Activity of Nanosized Particles of Nickel-Promoted Molybdenum Disulfide in the Hydroconversion Process View Full Text


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Article Info

DATE

2018-08

AUTHORS

Kh. M. Kadiev, A. M. Gyul’maliev, M. Kh. Kadieva, S. N. Khadzhiev, A. E. Batov

ABSTRACT

The paper is devoted to the investigation of the catalytic properties of nickel-promoted molybdenum disulfide nanoparticles in the hydroconversion process. The formation of Mo and Ni compounds under hydroconversion conditions has been studied using chemical thermodynamics methods. Quantum-chemical calculations in the cluster approximation have confirmed the catalytic activity of MonNimSp nanoparticles in the reactions of hydrogen activation and aromatic-ring hydrogenation. It has been shown that the main role in the activation of hydrogen and the hydrogenation of aromatic rings is played by Mo- and Ni-containing active sites of the catalyst, respectively. To confirm theoretical assumptions, the yield of products of fuel oil hydroconversion on nanosized particles of the catalyst, nickel-promoted and in situ formed molybdenum disulfide, has been investigated. It has been shown that the promotion with nickel enhances the hydrogenating functions of the molybdenum-containing catalyst and lowers coke formation during hydroconversion. More... »

PAGES

638-645

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544118080091

DOI

http://dx.doi.org/10.1134/s0965544118080091

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1105673008


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