Nickel–molybdenum sulfide catalysts supported on an ordered mesoporous polymer for hydrogenating–hydrocracking of model biaromatic petroleum compounds View Full Text


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Article Info

DATE

2017-08

AUTHORS

E. A. Karakhanov, M. P. Boronoev, V. I. Ignat’eva, Yu. S. Kardasheva, T. Yu. Filippova, A. L. Maksimov

ABSTRACT

Nickel–molybdenum sulfide catalysts have been synthesized in situ in a hydrocarbon medium by the decomposition of the [(n-Bu)4N]2Ni(MoS4)2 precursor complex supported on an ordered mesoporous phenol–formaldehyde polymer in the presence of a sulfiding agent (dimethyl disulfide). The catalytic properties of the samples have been studied in a batch reactor at 380°C and a hydrogen pressure of 5.0 MPa using the example of naphthalene, 1-methylnaphthalene, and 2-methylnaphthalene. The tests have shown that the conversion of biaromatic substrates is close to quantitative and the use of dimethyl disulfide as a sulfiding agent leads to an increase in the amount of complete hydrogenation products, as evidenced by the high content of the active phase in this case. More... »

PAGES

673-677

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544117080060

DOI

http://dx.doi.org/10.1134/s0965544117080060

DIMENSIONS

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