Methanol synthesis in a three-phase slurry reactor with ultrafine catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-07

AUTHORS

M. I. Ivantsov, M. V. Kulikova, M. A. Gubanov, O. S. Dement’eva, M. V. Chudakova, G. N. Bondarenko, S. N. Khadzhiev

ABSTRACT

It is shown that the effective synthesis of methanol may be performed in the presence of ultrafine catalyst systems formed by drop thermolysis in situ in a slurry reactor. Using the X-ray powder diffraction and FTIR spectroscopy data on the evolution of Cu–Zn–Al-containing catalyst dispersion during activation and catalysis, possible reasons for ultrafine catalyst deactivation are considered. More... »

PAGES

571-575

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544117070027

DOI

http://dx.doi.org/10.1134/s0965544117070027

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090603883


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ivantsov", 
        "givenName": "M. I.", 
        "id": "sg:person.016613745511.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016613745511.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kulikova", 
        "givenName": "M. V.", 
        "id": "sg:person.011441232771.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011441232771.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gubanov", 
        "givenName": "M. A.", 
        "id": "sg:person.013542664462.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013542664462.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dement\u2019eva", 
        "givenName": "O. S.", 
        "id": "sg:person.012611105146.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611105146.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chudakova", 
        "givenName": "M. V.", 
        "id": "sg:person.016272421333.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016272421333.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bondarenko", 
        "givenName": "G. N.", 
        "id": "sg:person.016522422357.89", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016522422357.89"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A.V.Topchiev Institute of Petrochemical Synthesis", 
          "id": "https://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Khadzhiev", 
        "givenName": "S. N.", 
        "id": "sg:person.01332170507.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01332170507.75"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/01614949408013929", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002690652"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b908034a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034448740"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b908034a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034448740"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s096554411401006x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040966746", 
          "https://doi.org/10.1134/s096554411401006x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2008.07.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043266104"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1997.1629", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046365291"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544116020079", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050399922", 
          "https://doi.org/10.1134/s0965544116020079"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544116120033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083752855", 
          "https://doi.org/10.1134/s0965544116120033"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544116120033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083752855", 
          "https://doi.org/10.1134/s0965544116120033"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-07", 
    "datePublishedReg": "2017-07-01", 
    "description": "It is shown that the effective synthesis of methanol may be performed in the presence of ultrafine catalyst systems formed by drop thermolysis in situ in a slurry reactor. Using the X-ray powder diffraction and FTIR spectroscopy data on the evolution of Cu\u2013Zn\u2013Al-containing catalyst dispersion during activation and catalysis, possible reasons for ultrafine catalyst deactivation are considered.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0965544117070027", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136087", 
        "issn": [
          "0965-5441", 
          "1555-6239"
        ], 
        "name": "Petroleum Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "57"
      }
    ], 
    "name": "Methanol synthesis in a three-phase slurry reactor with ultrafine catalysts", 
    "pagination": "571-575", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "6870ed574931058f8e156cb48d3d369cb8fbe47214368d34b4d2e7d8cd56263c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965544117070027"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1090603883"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965544117070027", 
      "https://app.dimensions.ai/details/publication/pub.1090603883"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:47", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000493.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0965544117070027"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965544117070027'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965544117070027'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965544117070027'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965544117070027'


 

This table displays all metadata directly associated to this object as RDF triples.

127 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965544117070027 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N4eb23228e40040b9ac1fc2cb030a903d
4 schema:citation sg:pub.10.1134/s096554411401006x
5 sg:pub.10.1134/s0965544116020079
6 sg:pub.10.1134/s0965544116120033
7 https://doi.org/10.1006/jcat.1997.1629
8 https://doi.org/10.1016/j.jcat.2008.07.004
9 https://doi.org/10.1039/b908034a
10 https://doi.org/10.1080/01614949408013929
11 schema:datePublished 2017-07
12 schema:datePublishedReg 2017-07-01
13 schema:description It is shown that the effective synthesis of methanol may be performed in the presence of ultrafine catalyst systems formed by drop thermolysis in situ in a slurry reactor. Using the X-ray powder diffraction and FTIR spectroscopy data on the evolution of Cu–Zn–Al-containing catalyst dispersion during activation and catalysis, possible reasons for ultrafine catalyst deactivation are considered.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N4216381a76e5497da05e93f91b664e91
18 Nf4c3d57da362492bb11e85b5bb726c66
19 sg:journal.1136087
20 schema:name Methanol synthesis in a three-phase slurry reactor with ultrafine catalysts
21 schema:pagination 571-575
22 schema:productId N0400e654398846df90d35ecdacaff00f
23 N7ede1476b70446d3847f5f0f97d0a498
24 Nda6aac94523c4a98a638a21e38737602
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090603883
26 https://doi.org/10.1134/s0965544117070027
27 schema:sdDatePublished 2019-04-10T15:47
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher Nde4fe73c2efe46b78a2d8b464e972535
30 schema:url http://link.springer.com/10.1134/S0965544117070027
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N0400e654398846df90d35ecdacaff00f schema:name readcube_id
35 schema:value 6870ed574931058f8e156cb48d3d369cb8fbe47214368d34b4d2e7d8cd56263c
36 rdf:type schema:PropertyValue
37 N13833f4a8820410f8cff0c9b0e9aac99 rdf:first sg:person.011441232771.03
38 rdf:rest Ncf259e9c79cd4bb8ae671de551b8fa02
39 N4216381a76e5497da05e93f91b664e91 schema:issueNumber 7
40 rdf:type schema:PublicationIssue
41 N48f6305e64a94a37a6e95ca463044bd0 rdf:first sg:person.016272421333.01
42 rdf:rest N939eda34c19340e5ab6a83abadddc15f
43 N4eb23228e40040b9ac1fc2cb030a903d rdf:first sg:person.016613745511.06
44 rdf:rest N13833f4a8820410f8cff0c9b0e9aac99
45 N600a33f5b26444f29f097aee133e8e72 rdf:first sg:person.01332170507.75
46 rdf:rest rdf:nil
47 N7ede1476b70446d3847f5f0f97d0a498 schema:name doi
48 schema:value 10.1134/s0965544117070027
49 rdf:type schema:PropertyValue
50 N939eda34c19340e5ab6a83abadddc15f rdf:first sg:person.016522422357.89
51 rdf:rest N600a33f5b26444f29f097aee133e8e72
52 Ncf259e9c79cd4bb8ae671de551b8fa02 rdf:first sg:person.013542664462.63
53 rdf:rest Nfe6aa4e1e56848f4bb9a1a78c4f8cd1a
54 Nda6aac94523c4a98a638a21e38737602 schema:name dimensions_id
55 schema:value pub.1090603883
56 rdf:type schema:PropertyValue
57 Nde4fe73c2efe46b78a2d8b464e972535 schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 Nf4c3d57da362492bb11e85b5bb726c66 schema:volumeNumber 57
60 rdf:type schema:PublicationVolume
61 Nfe6aa4e1e56848f4bb9a1a78c4f8cd1a rdf:first sg:person.012611105146.28
62 rdf:rest N48f6305e64a94a37a6e95ca463044bd0
63 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
64 schema:name Chemical Sciences
65 rdf:type schema:DefinedTerm
66 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
67 schema:name Physical Chemistry (incl. Structural)
68 rdf:type schema:DefinedTerm
69 sg:journal.1136087 schema:issn 0965-5441
70 1555-6239
71 schema:name Petroleum Chemistry
72 rdf:type schema:Periodical
73 sg:person.011441232771.03 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
74 schema:familyName Kulikova
75 schema:givenName M. V.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011441232771.03
77 rdf:type schema:Person
78 sg:person.012611105146.28 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
79 schema:familyName Dement’eva
80 schema:givenName O. S.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012611105146.28
82 rdf:type schema:Person
83 sg:person.01332170507.75 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
84 schema:familyName Khadzhiev
85 schema:givenName S. N.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01332170507.75
87 rdf:type schema:Person
88 sg:person.013542664462.63 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
89 schema:familyName Gubanov
90 schema:givenName M. A.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013542664462.63
92 rdf:type schema:Person
93 sg:person.016272421333.01 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
94 schema:familyName Chudakova
95 schema:givenName M. V.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016272421333.01
97 rdf:type schema:Person
98 sg:person.016522422357.89 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
99 schema:familyName Bondarenko
100 schema:givenName G. N.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016522422357.89
102 rdf:type schema:Person
103 sg:person.016613745511.06 schema:affiliation https://www.grid.ac/institutes/grid.423490.8
104 schema:familyName Ivantsov
105 schema:givenName M. I.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016613745511.06
107 rdf:type schema:Person
108 sg:pub.10.1134/s096554411401006x schema:sameAs https://app.dimensions.ai/details/publication/pub.1040966746
109 https://doi.org/10.1134/s096554411401006x
110 rdf:type schema:CreativeWork
111 sg:pub.10.1134/s0965544116020079 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050399922
112 https://doi.org/10.1134/s0965544116020079
113 rdf:type schema:CreativeWork
114 sg:pub.10.1134/s0965544116120033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1083752855
115 https://doi.org/10.1134/s0965544116120033
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1006/jcat.1997.1629 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046365291
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/j.jcat.2008.07.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043266104
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1039/b908034a schema:sameAs https://app.dimensions.ai/details/publication/pub.1034448740
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1080/01614949408013929 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002690652
124 rdf:type schema:CreativeWork
125 https://www.grid.ac/institutes/grid.423490.8 schema:alternateName A.V.Topchiev Institute of Petrochemical Synthesis
126 schema:name Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
127 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...