Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-12

AUTHORS

E. R. Naranov, O. V. Golubev, A. I. Guseva, P. A. Nikulshin, A. L. Maksimov, E. A. Karakhanov

ABSTRACT

The effect of the impregnation stage on the synthesis of NiW sulfide catalysts supported on the ZSM-5 zeolite has been studied. The hydrodearomatization (HDA) of light cycle oil (LCO) in the presence of a catalyst containing nickel and tungsten sulfides as an active phase impregnated onto a micro/mesoporous ZSM-5/SBA-15 support has been conducted. The catalyst has been compared with a commercial AGKD-400 diesel hydrotreating catalyst. It has been found that the impregnation of the supports with a solution containing an oxalic acid additive leads to an improvement in the morphology and composition of the active phase. The deepest hydrogenation is observed at 360°C, 6 MPa H2, and a LHSV = 0.5 h–1. The amount of diaromatic hydrocarbons decreases 12-fold, and the sulfur content decreases by 90%. More... »

PAGES

1151-1155

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544117060226

DOI

http://dx.doi.org/10.1134/s0965544117060226

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101064498


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Moscow, Russia", 
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Naranov", 
        "givenName": "E. R.", 
        "id": "sg:person.014700162746.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014700162746.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Golubev", 
        "givenName": "O. V.", 
        "id": "sg:person.011653160604.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011653160604.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "All-Russia Research Institute for Oil Refining, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "All-Russia Research Institute for Oil Refining, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Guseva", 
        "givenName": "A. I.", 
        "id": "sg:person.012156601204.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012156601204.13"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "All-Russia Research Institute for Oil Refining, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "All-Russia Research Institute for Oil Refining, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nikulshin", 
        "givenName": "P. A.", 
        "id": "sg:person.016526431035.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016526431035.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Moscow, Russia", 
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maksimov", 
        "givenName": "A. L.", 
        "id": "sg:person.07570312367.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07570312367.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Karakhanov", 
        "givenName": "E. A.", 
        "id": "sg:person.07630703323.87", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07630703323.87"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0965544116070124", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048401065", 
          "https://doi.org/10.1134/s0965544116070124"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-12", 
    "datePublishedReg": "2017-12-01", 
    "description": "The effect of the impregnation stage on the synthesis of NiW sulfide catalysts supported on the ZSM-5 zeolite has been studied. The hydrodearomatization (HDA) of light cycle oil (LCO) in the presence of a catalyst containing nickel and tungsten sulfides as an active phase impregnated onto a micro/mesoporous ZSM-5/SBA-15 support has been conducted. The catalyst has been compared with a commercial AGKD-400 diesel hydrotreating catalyst. It has been found that the impregnation of the supports with a solution containing an oxalic acid additive leads to an improvement in the morphology and composition of the active phase. The deepest hydrogenation is observed at 360\u00b0C, 6 MPa H2, and a LHSV = 0.5 h\u20131. The amount of diaromatic hydrocarbons decreases 12-fold, and the sulfur content decreases by 90%.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0965544117060226", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136087", 
        "issn": [
          "0965-5441", 
          "1555-6239"
        ], 
        "name": "Petroleum Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "57"
      }
    ], 
    "keywords": [
      "light cycle oil", 
      "middle-distillate fractions", 
      "NiW sulfide catalysts", 
      "active phase", 
      "sulfide catalysts", 
      "hydrotreating catalysts", 
      "porous aluminosilicates", 
      "tungsten sulfide", 
      "ZSM-5 zeolite", 
      "deep hydrogenation", 
      "catalyst", 
      "cycle oil", 
      "additive leads", 
      "MPa H2", 
      "hydrodearomatization", 
      "sulfur content", 
      "sulfide", 
      "diaromatic hydrocarbons", 
      "impregnation stage", 
      "hydrotreating", 
      "zeolite", 
      "hydrogenation", 
      "LHSV", 
      "aluminosilicates", 
      "impregnation", 
      "synthesis", 
      "nickel", 
      "H2", 
      "hydrocarbons", 
      "phase", 
      "morphology", 
      "oil", 
      "solution", 
      "composition", 
      "lead", 
      "amount", 
      "h-1", 
      "presence", 
      "fraction", 
      "content", 
      "support", 
      "effect", 
      "improvement", 
      "stage", 
      "mesoporous ZSM-5/SBA-15 support", 
      "ZSM-5/SBA-15 support", 
      "SBA-15 support", 
      "commercial AGKD-400 diesel hydrotreating catalyst", 
      "AGKD-400 diesel hydrotreating catalyst", 
      "diesel hydrotreating catalyst", 
      "oxalic acid additive leads", 
      "acid additive leads", 
      "Crystalline Porous Aluminosilicates"
    ], 
    "name": "Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates", 
    "pagination": "1151-1155", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1101064498"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965544117060226"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965544117060226", 
      "https://app.dimensions.ai/details/publication/pub.1101064498"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:37", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_727.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0965544117060226"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965544117060226'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965544117060226'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965544117060226'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965544117060226'


 

This table displays all metadata directly associated to this object as RDF triples.

157 TRIPLES      22 PREDICATES      80 URIs      71 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965544117060226 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author N28a3b8506ffe4418a46e3d898c934156
4 schema:citation sg:pub.10.1134/s0965544116070124
5 schema:datePublished 2017-12
6 schema:datePublishedReg 2017-12-01
7 schema:description The effect of the impregnation stage on the synthesis of NiW sulfide catalysts supported on the ZSM-5 zeolite has been studied. The hydrodearomatization (HDA) of light cycle oil (LCO) in the presence of a catalyst containing nickel and tungsten sulfides as an active phase impregnated onto a micro/mesoporous ZSM-5/SBA-15 support has been conducted. The catalyst has been compared with a commercial AGKD-400 diesel hydrotreating catalyst. It has been found that the impregnation of the supports with a solution containing an oxalic acid additive leads to an improvement in the morphology and composition of the active phase. The deepest hydrogenation is observed at 360°C, 6 MPa H2, and a LHSV = 0.5 h–1. The amount of diaromatic hydrocarbons decreases 12-fold, and the sulfur content decreases by 90%.
8 schema:genre article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N335cd958b59d48498ebfb504b035e897
12 N53eebed9a0b9423f8604e45d1f07d79e
13 sg:journal.1136087
14 schema:keywords AGKD-400 diesel hydrotreating catalyst
15 Crystalline Porous Aluminosilicates
16 H2
17 LHSV
18 MPa H2
19 NiW sulfide catalysts
20 SBA-15 support
21 ZSM-5 zeolite
22 ZSM-5/SBA-15 support
23 acid additive leads
24 active phase
25 additive leads
26 aluminosilicates
27 amount
28 catalyst
29 commercial AGKD-400 diesel hydrotreating catalyst
30 composition
31 content
32 cycle oil
33 deep hydrogenation
34 diaromatic hydrocarbons
35 diesel hydrotreating catalyst
36 effect
37 fraction
38 h-1
39 hydrocarbons
40 hydrodearomatization
41 hydrogenation
42 hydrotreating
43 hydrotreating catalysts
44 impregnation
45 impregnation stage
46 improvement
47 lead
48 light cycle oil
49 mesoporous ZSM-5/SBA-15 support
50 middle-distillate fractions
51 morphology
52 nickel
53 oil
54 oxalic acid additive leads
55 phase
56 porous aluminosilicates
57 presence
58 solution
59 stage
60 sulfide
61 sulfide catalysts
62 sulfur content
63 support
64 synthesis
65 tungsten sulfide
66 zeolite
67 schema:name Hydrotreating of Middle-Distillate Fraction on Sulfide Catalysts Containing Crystalline Porous Aluminosilicates
68 schema:pagination 1151-1155
69 schema:productId N791acece40654f34ab9899d5fa6bb36d
70 Nff07f3d906d04facb09cfcd837e31fe8
71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1101064498
72 https://doi.org/10.1134/s0965544117060226
73 schema:sdDatePublished 2021-12-01T19:37
74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
75 schema:sdPublisher Ndc2b944b4e48446eafeec75171656844
76 schema:url https://doi.org/10.1134/s0965544117060226
77 sgo:license sg:explorer/license/
78 sgo:sdDataset articles
79 rdf:type schema:ScholarlyArticle
80 N1646d8e48a6443bcba1ef624977529b2 rdf:first sg:person.016526431035.10
81 rdf:rest N1b70551ac98540ff905d693ecf151693
82 N1b70551ac98540ff905d693ecf151693 rdf:first sg:person.07570312367.72
83 rdf:rest N5e15c27f07254d8f980885ac0553f18d
84 N28a3b8506ffe4418a46e3d898c934156 rdf:first sg:person.014700162746.91
85 rdf:rest Nfe51e97cc2154f2ea6219f3cb15d92f8
86 N335cd958b59d48498ebfb504b035e897 schema:issueNumber 12
87 rdf:type schema:PublicationIssue
88 N53eebed9a0b9423f8604e45d1f07d79e schema:volumeNumber 57
89 rdf:type schema:PublicationVolume
90 N5e15c27f07254d8f980885ac0553f18d rdf:first sg:person.07630703323.87
91 rdf:rest rdf:nil
92 N791acece40654f34ab9899d5fa6bb36d schema:name doi
93 schema:value 10.1134/s0965544117060226
94 rdf:type schema:PropertyValue
95 N9e506887bf7949159185e328be8a8031 rdf:first sg:person.012156601204.13
96 rdf:rest N1646d8e48a6443bcba1ef624977529b2
97 Ndc2b944b4e48446eafeec75171656844 schema:name Springer Nature - SN SciGraph project
98 rdf:type schema:Organization
99 Nfe51e97cc2154f2ea6219f3cb15d92f8 rdf:first sg:person.011653160604.11
100 rdf:rest N9e506887bf7949159185e328be8a8031
101 Nff07f3d906d04facb09cfcd837e31fe8 schema:name dimensions_id
102 schema:value pub.1101064498
103 rdf:type schema:PropertyValue
104 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
105 schema:name Engineering
106 rdf:type schema:DefinedTerm
107 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
108 schema:name Chemical Engineering
109 rdf:type schema:DefinedTerm
110 sg:journal.1136087 schema:issn 0965-5441
111 1555-6239
112 schema:name Petroleum Chemistry
113 schema:publisher Pleiades Publishing
114 rdf:type schema:Periodical
115 sg:person.011653160604.11 schema:affiliation grid-institutes:grid.14476.30
116 schema:familyName Golubev
117 schema:givenName O. V.
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011653160604.11
119 rdf:type schema:Person
120 sg:person.012156601204.13 schema:affiliation grid-institutes:None
121 schema:familyName Guseva
122 schema:givenName A. I.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012156601204.13
124 rdf:type schema:Person
125 sg:person.014700162746.91 schema:affiliation grid-institutes:grid.423490.8
126 schema:familyName Naranov
127 schema:givenName E. R.
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014700162746.91
129 rdf:type schema:Person
130 sg:person.016526431035.10 schema:affiliation grid-institutes:None
131 schema:familyName Nikulshin
132 schema:givenName P. A.
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016526431035.10
134 rdf:type schema:Person
135 sg:person.07570312367.72 schema:affiliation grid-institutes:grid.423490.8
136 schema:familyName Maksimov
137 schema:givenName A. L.
138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07570312367.72
139 rdf:type schema:Person
140 sg:person.07630703323.87 schema:affiliation grid-institutes:grid.14476.30
141 schema:familyName Karakhanov
142 schema:givenName E. A.
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07630703323.87
144 rdf:type schema:Person
145 sg:pub.10.1134/s0965544116070124 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048401065
146 https://doi.org/10.1134/s0965544116070124
147 rdf:type schema:CreativeWork
148 grid-institutes:None schema:alternateName All-Russia Research Institute for Oil Refining, Moscow, Russia
149 schema:name All-Russia Research Institute for Oil Refining, Moscow, Russia
150 rdf:type schema:Organization
151 grid-institutes:grid.14476.30 schema:alternateName Faculty of Chemistry, Moscow State University, Moscow, Russia
152 schema:name Faculty of Chemistry, Moscow State University, Moscow, Russia
153 rdf:type schema:Organization
154 grid-institutes:grid.423490.8 schema:alternateName Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
155 schema:name Faculty of Chemistry, Moscow State University, Moscow, Russia
156 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
157 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...