Dichlorocarbenation of conjugated diene hydrocarbons View Full Text


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Article Info

DATE

2017-03

AUTHORS

G. Z. Raskil’dina, Yu. G. Borisova, V. M. Yanybin, S. S. Zlotskii

ABSTRACT

Partial and complete dichlorocarbenation of conjugated diene hydrocarbons in the presence of the phase-transfer catalyst catamine AB has been studied. It has been shown that at the initial stages of the process (conversion of the reactant olefins below 30%), alkenyl-gem-dichlorocyclopropanes are the main products. In the case of complete carbenation, corresponding bicyclic structures are formed. The structures of the resulting stereoisomers have been described in detail using 1H and 13С NMR methods. The relative reactivity of the initial dienes has been determined using a method of competitive kinetics. More... »

PAGES

278-283

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544117020219

DOI

http://dx.doi.org/10.1134/s0965544117020219

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084608342


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