Hydrofining of light cycle oil over in situ synthesized nickel–tungsten sulfide catalysts View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-06

AUTHORS

I. A. Sizova, A. L. Maksimov

ABSTRACT

Nickel–tungsten sulfide catalysts for the hydrogenation and hydrodesulfurization of aromatic hydrocarbons are synthesized by the in situ decomposition of thio salts using different methods: the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in an ionic liquid, the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in a hydrocarbon feedstock, the in situ breaking of a SPAN-80 surfactant-stabilized suspension of solid Ni/(NH4)2WS4 precursor particles in a hydrocarbon feedstock, and the decomposition of oil-soluble precursors (tungsten hexacarbonyl and nickel(II) 2-ethylhexanoate) in a hydrocarbon feedstock. The resulting catalysts are characterized by X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy; their catalytic activity is studied in a batch reactor using the example of the hydrofining of light cycle oils with different compositions. More... »

PAGES

510-521

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544116060098

DOI

http://dx.doi.org/10.1134/s0965544116060098

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034158777


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