Hydrofining of light cycle oil over in situ synthesized nickel–tungsten sulfide catalysts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-06

AUTHORS

I. A. Sizova, A. L. Maksimov

ABSTRACT

Nickel–tungsten sulfide catalysts for the hydrogenation and hydrodesulfurization of aromatic hydrocarbons are synthesized by the in situ decomposition of thio salts using different methods: the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in an ionic liquid, the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in a hydrocarbon feedstock, the in situ breaking of a SPAN-80 surfactant-stabilized suspension of solid Ni/(NH4)2WS4 precursor particles in a hydrocarbon feedstock, and the decomposition of oil-soluble precursors (tungsten hexacarbonyl and nickel(II) 2-ethylhexanoate) in a hydrocarbon feedstock. The resulting catalysts are characterized by X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy; their catalytic activity is studied in a batch reactor using the example of the hydrofining of light cycle oils with different compositions. More... »

PAGES

510-521

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544116060098

DOI

http://dx.doi.org/10.1134/s0965544116060098

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034158777


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sizova", 
        "givenName": "I. A.", 
        "id": "sg:person.07772410325.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07772410325.17"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Moscow State University, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
            "Department of Chemistry, Moscow State University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maksimov", 
        "givenName": "A. L.", 
        "id": "sg:person.07570312367.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07570312367.72"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0965544115010120", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013976539", 
          "https://doi.org/10.1134/s0965544115010120"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544116020134", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031079370", 
          "https://doi.org/10.1134/s0965544116020134"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544115080174", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035764041", 
          "https://doi.org/10.1134/s0965544115080174"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11244-010-9515-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001113396", 
          "https://doi.org/10.1007/s11244-010-9515-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544115060110", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016178267", 
          "https://doi.org/10.1134/s0965544115060110"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-06", 
    "datePublishedReg": "2016-06-01", 
    "description": "Nickel\u2013tungsten sulfide catalysts for the hydrogenation and hydrodesulfurization of aromatic hydrocarbons are synthesized by the in situ decomposition of thio salts using different methods: the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in an ionic liquid, the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in a hydrocarbon feedstock, the in situ breaking of a SPAN-80 surfactant-stabilized suspension of solid Ni/(NH4)2WS4 precursor particles in a hydrocarbon feedstock, and the decomposition of oil-soluble precursors (tungsten hexacarbonyl and nickel(II) 2-ethylhexanoate) in a hydrocarbon feedstock. The resulting catalysts are characterized by X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy; their catalytic activity is studied in a batch reactor using the example of the hydrofining of light cycle oils with different compositions.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0965544116060098", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136087", 
        "issn": [
          "0965-5441", 
          "1555-6239"
        ], 
        "name": "Petroleum Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "keywords": [
      "light cycle oil", 
      "hydrocarbon feedstock", 
      "situ decomposition", 
      "cycle oil", 
      "oil-soluble precursors", 
      "nickel-tungsten sulfide catalysts", 
      "nickel-tungsten sulfide", 
      "ray photoelectron spectroscopy", 
      "high-resolution transmission electron microscopy", 
      "ionic liquids", 
      "sulfide catalysts", 
      "photoelectron spectroscopy", 
      "catalytic activity", 
      "transmission electron microscopy", 
      "precursor particles", 
      "catalyst", 
      "batch reactor", 
      "electron microscopy", 
      "aromatic hydrocarbons", 
      "different compositions", 
      "precursors", 
      "feedstock", 
      "decomposition", 
      "hydrodesulfurization", 
      "hydrogenation", 
      "spectroscopy", 
      "hydrofining", 
      "thio salts", 
      "oil", 
      "salt", 
      "sulfide", 
      "hydrocarbons", 
      "liquid", 
      "reactor", 
      "microscopy", 
      "different methods", 
      "particles", 
      "situ", 
      "composition", 
      "suspension", 
      "breaking", 
      "method", 
      "activity", 
      "example", 
      "situ breaking", 
      "SPAN-80 surfactant-stabilized suspension", 
      "surfactant-stabilized suspension"
    ], 
    "name": "Hydrofining of light cycle oil over in situ synthesized nickel\u2013tungsten sulfide catalysts", 
    "pagination": "510-521", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1034158777"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965544116060098"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965544116060098", 
      "https://app.dimensions.ai/details/publication/pub.1034158777"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:36", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_706.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0965544116060098"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965544116060098'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965544116060098'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965544116060098'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965544116060098'


 

This table displays all metadata directly associated to this object as RDF triples.

136 TRIPLES      22 PREDICATES      78 URIs      65 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965544116060098 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author N4536fa93df5c46c485b6dd48fe47aabd
4 schema:citation sg:pub.10.1007/s11244-010-9515-7
5 sg:pub.10.1134/s0965544115010120
6 sg:pub.10.1134/s0965544115060110
7 sg:pub.10.1134/s0965544115080174
8 sg:pub.10.1134/s0965544116020134
9 schema:datePublished 2016-06
10 schema:datePublishedReg 2016-06-01
11 schema:description Nickel–tungsten sulfide catalysts for the hydrogenation and hydrodesulfurization of aromatic hydrocarbons are synthesized by the in situ decomposition of thio salts using different methods: the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in an ionic liquid, the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in a hydrocarbon feedstock, the in situ breaking of a SPAN-80 surfactant-stabilized suspension of solid Ni/(NH4)2WS4 precursor particles in a hydrocarbon feedstock, and the decomposition of oil-soluble precursors (tungsten hexacarbonyl and nickel(II) 2-ethylhexanoate) in a hydrocarbon feedstock. The resulting catalysts are characterized by X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy; their catalytic activity is studied in a batch reactor using the example of the hydrofining of light cycle oils with different compositions.
12 schema:genre article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N4d32b3c4ef324859a31aea1153a19eff
16 Nce12c0b5283f490489980480d4b6442b
17 sg:journal.1136087
18 schema:keywords SPAN-80 surfactant-stabilized suspension
19 activity
20 aromatic hydrocarbons
21 batch reactor
22 breaking
23 catalyst
24 catalytic activity
25 composition
26 cycle oil
27 decomposition
28 different compositions
29 different methods
30 electron microscopy
31 example
32 feedstock
33 high-resolution transmission electron microscopy
34 hydrocarbon feedstock
35 hydrocarbons
36 hydrodesulfurization
37 hydrofining
38 hydrogenation
39 ionic liquids
40 light cycle oil
41 liquid
42 method
43 microscopy
44 nickel-tungsten sulfide
45 nickel-tungsten sulfide catalysts
46 oil
47 oil-soluble precursors
48 particles
49 photoelectron spectroscopy
50 precursor particles
51 precursors
52 ray photoelectron spectroscopy
53 reactor
54 salt
55 situ
56 situ breaking
57 situ decomposition
58 spectroscopy
59 sulfide
60 sulfide catalysts
61 surfactant-stabilized suspension
62 suspension
63 thio salts
64 transmission electron microscopy
65 schema:name Hydrofining of light cycle oil over in situ synthesized nickel–tungsten sulfide catalysts
66 schema:pagination 510-521
67 schema:productId Nb9ea2d5ac56645eea6236b5ab988740e
68 Ne1fbbb6a444c423094e48ed2d4879562
69 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034158777
70 https://doi.org/10.1134/s0965544116060098
71 schema:sdDatePublished 2021-12-01T19:36
72 schema:sdLicense https://scigraph.springernature.com/explorer/license/
73 schema:sdPublisher Nd5d71be8ecfb47d0b13094eb9a8751c8
74 schema:url https://doi.org/10.1134/s0965544116060098
75 sgo:license sg:explorer/license/
76 sgo:sdDataset articles
77 rdf:type schema:ScholarlyArticle
78 N4536fa93df5c46c485b6dd48fe47aabd rdf:first sg:person.07772410325.17
79 rdf:rest Nd7237fbefad14f17ad6363fee032250e
80 N4d32b3c4ef324859a31aea1153a19eff schema:issueNumber 6
81 rdf:type schema:PublicationIssue
82 Nb9ea2d5ac56645eea6236b5ab988740e schema:name doi
83 schema:value 10.1134/s0965544116060098
84 rdf:type schema:PropertyValue
85 Nce12c0b5283f490489980480d4b6442b schema:volumeNumber 56
86 rdf:type schema:PublicationVolume
87 Nd5d71be8ecfb47d0b13094eb9a8751c8 schema:name Springer Nature - SN SciGraph project
88 rdf:type schema:Organization
89 Nd7237fbefad14f17ad6363fee032250e rdf:first sg:person.07570312367.72
90 rdf:rest rdf:nil
91 Ne1fbbb6a444c423094e48ed2d4879562 schema:name dimensions_id
92 schema:value pub.1034158777
93 rdf:type schema:PropertyValue
94 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
95 schema:name Engineering
96 rdf:type schema:DefinedTerm
97 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
98 schema:name Chemical Engineering
99 rdf:type schema:DefinedTerm
100 sg:journal.1136087 schema:issn 0965-5441
101 1555-6239
102 schema:name Petroleum Chemistry
103 schema:publisher Pleiades Publishing
104 rdf:type schema:Periodical
105 sg:person.07570312367.72 schema:affiliation grid-institutes:grid.14476.30
106 schema:familyName Maksimov
107 schema:givenName A. L.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07570312367.72
109 rdf:type schema:Person
110 sg:person.07772410325.17 schema:affiliation grid-institutes:grid.423490.8
111 schema:familyName Sizova
112 schema:givenName I. A.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07772410325.17
114 rdf:type schema:Person
115 sg:pub.10.1007/s11244-010-9515-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001113396
116 https://doi.org/10.1007/s11244-010-9515-7
117 rdf:type schema:CreativeWork
118 sg:pub.10.1134/s0965544115010120 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013976539
119 https://doi.org/10.1134/s0965544115010120
120 rdf:type schema:CreativeWork
121 sg:pub.10.1134/s0965544115060110 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016178267
122 https://doi.org/10.1134/s0965544115060110
123 rdf:type schema:CreativeWork
124 sg:pub.10.1134/s0965544115080174 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035764041
125 https://doi.org/10.1134/s0965544115080174
126 rdf:type schema:CreativeWork
127 sg:pub.10.1134/s0965544116020134 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031079370
128 https://doi.org/10.1134/s0965544116020134
129 rdf:type schema:CreativeWork
130 grid-institutes:grid.14476.30 schema:alternateName Department of Chemistry, Moscow State University, Moscow, Russia
131 schema:name Department of Chemistry, Moscow State University, Moscow, Russia
132 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
133 rdf:type schema:Organization
134 grid-institutes:grid.423490.8 schema:alternateName Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
135 schema:name Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
136 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...