New heterogeneous catalysts based on zeolites with hierarchical pore system View Full Text


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Article Info

DATE

2016-03

AUTHORS

E. V. Parkhomchuk, K. A. Sashkina, V. N. Parmon

ABSTRACT

The results of synthesis and packing of crystallized iron-containing nanosized zeolites of MFI structure in dense and loose structures having different textural properties are reported. Data on the formation of additional meso- and macropores immediately during zeolite crystallization using polystyrene microspheres in the form of an aqueous suspension (latex) and as a dry template of closely packed particles are also presented. Advantages and disadvantages of these procedures for preparing hierarchical iron-containing MFI structure zeolites have been compared. Values of the external surface area and the total pore volume of hierarchical Fe-silicalites are significantly higher than those for a reference sample. Using the polymer template to synthesize the hierarchical material consisting of zeolite nanocrystals makes it possible can significantly reduce the synthesis time and simplify the preparation procedure. More... »

PAGES

197-204

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544116030105

DOI

http://dx.doi.org/10.1134/s0965544116030105

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033113468


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