Heterogeneous catalytic conversion of glycerol with n-butyl alcohol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-02

AUTHORS

V. O. Samoilov, D. N. Ramazanov, A. I. Nekhaev, A. L. Maksimov

ABSTRACT

The etherification of glycerol with n-butyl alcohol at 140°C in the presence of sulfonated cation-exchange resins and zeolite catalysts in an autoclave reactor has been studied. It has been shown that styrene—divinylbenzene ion-exchange resins are effective catalysts for the production of glycerol n-butyl ethers: the glycerol conversion is about 98% with an n-butyl ether selectivity of about 88 mol % (140°C, 5 h, 5 wt % Amberlyst 36 catalyst, and 10 wt % glycerol in n-butanol). Zeolites Y and β in the H+ form exhibit comparable specific activity (glycerol conversion of no more than 25% under similar conditions) in combination with high selectivity for glycerol di-n-butyl ethers (up to 28%). More... »

PAGES

125-130

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544116010060

DOI

http://dx.doi.org/10.1134/s0965544116010060

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031825815


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