On the mechanism and main features of hydroconversion of the organic matter of oil sludge in the presence of nanosized ... View Full Text


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Article Info

DATE

2015-09-03

AUTHORS

Kh. M. Kadiev, N. V. Oknina, A. M. Gyul’maliev, S. G. Gagarin, M. Kh. Kadieva, A. E. Batov, S. N. Khadzhiev

ABSTRACT

The features of hydroconversion of the organic matter of oil sludge have been analyzed by means of chemical thermodynamics and quantum chemistry using as an example the conversion of model organic compounds (aromatic structures, their alkylated and hydrogenated derivatives) in different media. The kinetic characteristics of hydrogenation and hydrogenolysis of the oil sludge have been analyzed in the fractionated feedstock model presented as four pseudocomponents. A scheme of sequential transformations of each of the pseudocomponents with effective rate constants is proposed, in which the rate constant values have been determined from the results of hydroconversion of oil products in a pilot flow reactor unit. More... »

PAGES

563-570

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544115070051

DOI

http://dx.doi.org/10.1134/s0965544115070051

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024830235


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