Structural transformations of asphaltenes during hydroconversion of vacuum residue with recycling the hydroconversion product distillation residue View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-07-07

AUTHORS

Kh. M. Kadiev, O. V. Zaytseva, E. E. Magomadov, E. A. Chernysheva, N. V. Oknina, A. E. Batov, M. Kh. Kadieva, V. M. Kapustin, S. N. Khadzhiev

ABSTRACT

The hydroconversion of vacuum residue (VR) with the recycle of the unconverted vacuum residue in the presence of nanosized MoS2 catalyst particles synthesized “in situ” in the hydrocarbon medium has been studied. Changes in the molecular structure of asphaltenes from VR and the products of VR hydroconversion in a mixture with the vacuum residue (recycle), depending on the residence time of asphaltenes in the reaction zone, have been described. The main features of structural transformations of asphaltenes during the hydroconversion with recycle have been established. Trends in the structural properties of the asphaltenes with varying different process parameters, such as the residence time and temperature in the reaction medium, have been compared. More... »

PAGES

487-496

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544115060067

DOI

http://dx.doi.org/10.1134/s0965544115060067

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006681319


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kadiev", 
        "givenName": "Kh. M.", 
        "id": "sg:person.012531050145.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012531050145.44"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Gubkin Russian State University of Oil and Gas, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.448924.7", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
            "Gubkin Russian State University of Oil and Gas, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zaytseva", 
        "givenName": "O. V.", 
        "id": "sg:person.011144042727.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011144042727.38"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Magomadov", 
        "givenName": "E. E.", 
        "id": "sg:person.010334416261.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010334416261.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Gubkin Russian State University of Oil and Gas, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.448924.7", 
          "name": [
            "Gubkin Russian State University of Oil and Gas, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chernysheva", 
        "givenName": "E. A.", 
        "id": "sg:person.010050175211.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010050175211.51"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Electrogorsk Institute of Petroleum Processing, Electrogorsk, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Electrogorsk Institute of Petroleum Processing, Electrogorsk, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Oknina", 
        "givenName": "N. V.", 
        "id": "sg:person.013334364327.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013334364327.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Batov", 
        "givenName": "A. E.", 
        "id": "sg:person.012257057735.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012257057735.83"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kadieva", 
        "givenName": "M. Kh.", 
        "id": "sg:person.010431675375.32", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010431675375.32"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Gubkin Russian State University of Oil and Gas, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.448924.7", 
          "name": [
            "Gubkin Russian State University of Oil and Gas, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kapustin", 
        "givenName": "V. M.", 
        "id": "sg:person.015361631601.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015361631601.61"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Khadzhiev", 
        "givenName": "S. N.", 
        "id": "sg:person.01332170507.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01332170507.75"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0965544111060077", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032326510", 
          "https://doi.org/10.1134/s0965544111060077"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544111010063", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005790346", 
          "https://doi.org/10.1134/s0965544111010063"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544111010051", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028976970", 
          "https://doi.org/10.1134/s0965544111010051"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544113050113", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004135902", 
          "https://doi.org/10.1134/s0965544113050113"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-07-07", 
    "datePublishedReg": "2015-07-07", 
    "description": "The hydroconversion of vacuum residue (VR) with the recycle of the unconverted vacuum residue in the presence of nanosized MoS2 catalyst particles synthesized \u201cin situ\u201d in the hydrocarbon medium has been studied. Changes in the molecular structure of asphaltenes from VR and the products of VR hydroconversion in a mixture with the vacuum residue (recycle), depending on the residence time of asphaltenes in the reaction zone, have been described. The main features of structural transformations of asphaltenes during the hydroconversion with recycle have been established. Trends in the structural properties of the asphaltenes with varying different process parameters, such as the residence time and temperature in the reaction medium, have been compared.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0965544115060067", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136087", 
        "issn": [
          "0965-5441", 
          "1555-6239"
        ], 
        "name": "Petroleum Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "55"
      }
    ], 
    "keywords": [
      "different process parameters", 
      "vacuum residue", 
      "residence time", 
      "process parameters", 
      "reaction zone", 
      "structural transformation", 
      "catalyst particles", 
      "recycle", 
      "structural properties", 
      "asphaltenes", 
      "distillation residue", 
      "hydrocarbon media", 
      "main features", 
      "hydroconversion", 
      "particles", 
      "temperature", 
      "properties", 
      "reaction medium", 
      "mixture", 
      "zone", 
      "situ", 
      "parameters", 
      "structure", 
      "medium", 
      "transformation", 
      "time", 
      "products", 
      "features", 
      "trends", 
      "presence", 
      "changes", 
      "molecular structure", 
      "residues", 
      "unconverted vacuum residue", 
      "MoS2 catalyst particles", 
      "VR hydroconversion", 
      "hydroconversion product distillation residue", 
      "product distillation residue"
    ], 
    "name": "Structural transformations of asphaltenes during hydroconversion of vacuum residue with recycling the hydroconversion product distillation residue", 
    "pagination": "487-496", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006681319"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0965544115060067"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0965544115060067", 
      "https://app.dimensions.ai/details/publication/pub.1006681319"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:36", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_657.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0965544115060067"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0965544115060067'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0965544115060067'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0965544115060067'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0965544115060067'


 

This table displays all metadata directly associated to this object as RDF triples.

175 TRIPLES      22 PREDICATES      67 URIs      55 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0965544115060067 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author N3b005725f74f4de1afa411701445b5e3
4 schema:citation sg:pub.10.1134/s0965544111010051
5 sg:pub.10.1134/s0965544111010063
6 sg:pub.10.1134/s0965544111060077
7 sg:pub.10.1134/s0965544113050113
8 schema:datePublished 2015-07-07
9 schema:datePublishedReg 2015-07-07
10 schema:description The hydroconversion of vacuum residue (VR) with the recycle of the unconverted vacuum residue in the presence of nanosized MoS2 catalyst particles synthesized “in situ” in the hydrocarbon medium has been studied. Changes in the molecular structure of asphaltenes from VR and the products of VR hydroconversion in a mixture with the vacuum residue (recycle), depending on the residence time of asphaltenes in the reaction zone, have been described. The main features of structural transformations of asphaltenes during the hydroconversion with recycle have been established. Trends in the structural properties of the asphaltenes with varying different process parameters, such as the residence time and temperature in the reaction medium, have been compared.
11 schema:genre article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N3079eeeb040f4e0191369f3c5189d3a8
15 N4a6d3217c43a4fc8b863b1e44bbc87ce
16 sg:journal.1136087
17 schema:keywords MoS2 catalyst particles
18 VR hydroconversion
19 asphaltenes
20 catalyst particles
21 changes
22 different process parameters
23 distillation residue
24 features
25 hydrocarbon media
26 hydroconversion
27 hydroconversion product distillation residue
28 main features
29 medium
30 mixture
31 molecular structure
32 parameters
33 particles
34 presence
35 process parameters
36 product distillation residue
37 products
38 properties
39 reaction medium
40 reaction zone
41 recycle
42 residence time
43 residues
44 situ
45 structural properties
46 structural transformation
47 structure
48 temperature
49 time
50 transformation
51 trends
52 unconverted vacuum residue
53 vacuum residue
54 zone
55 schema:name Structural transformations of asphaltenes during hydroconversion of vacuum residue with recycling the hydroconversion product distillation residue
56 schema:pagination 487-496
57 schema:productId N598a50861e59417b97278938bdb182f4
58 Nba41c8c5ab40432a9da59224199ab755
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006681319
60 https://doi.org/10.1134/s0965544115060067
61 schema:sdDatePublished 2022-01-01T18:36
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher Nfa0b7cfaaed745cba967a01a8f85bca5
64 schema:url https://doi.org/10.1134/s0965544115060067
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N047e713dd15449bd954a4287d5ed0cc5 rdf:first sg:person.015361631601.61
69 rdf:rest Nf0902bb1a0b747b388244e8087ff676b
70 N0c6ba82f0c7e45ddb642e31a4bba0ce1 rdf:first sg:person.013334364327.36
71 rdf:rest Nfe4fb25addff431abcd99d6144daf7ec
72 N3079eeeb040f4e0191369f3c5189d3a8 schema:issueNumber 6
73 rdf:type schema:PublicationIssue
74 N36dc86341fca4cf9bc417675eed494b8 rdf:first sg:person.010334416261.46
75 rdf:rest N4f0389a0d98245a08840c5a2b849af00
76 N3b005725f74f4de1afa411701445b5e3 rdf:first sg:person.012531050145.44
77 rdf:rest Na569b4a3c7da4c7a8e39ba8ce087330c
78 N4a6d3217c43a4fc8b863b1e44bbc87ce schema:volumeNumber 55
79 rdf:type schema:PublicationVolume
80 N4f0389a0d98245a08840c5a2b849af00 rdf:first sg:person.010050175211.51
81 rdf:rest N0c6ba82f0c7e45ddb642e31a4bba0ce1
82 N598a50861e59417b97278938bdb182f4 schema:name doi
83 schema:value 10.1134/s0965544115060067
84 rdf:type schema:PropertyValue
85 Na569b4a3c7da4c7a8e39ba8ce087330c rdf:first sg:person.011144042727.38
86 rdf:rest N36dc86341fca4cf9bc417675eed494b8
87 Nba41c8c5ab40432a9da59224199ab755 schema:name dimensions_id
88 schema:value pub.1006681319
89 rdf:type schema:PropertyValue
90 Nf0902bb1a0b747b388244e8087ff676b rdf:first sg:person.01332170507.75
91 rdf:rest rdf:nil
92 Nfa0b7cfaaed745cba967a01a8f85bca5 schema:name Springer Nature - SN SciGraph project
93 rdf:type schema:Organization
94 Nfb3f019749204420b422fc7f11184580 rdf:first sg:person.010431675375.32
95 rdf:rest N047e713dd15449bd954a4287d5ed0cc5
96 Nfe4fb25addff431abcd99d6144daf7ec rdf:first sg:person.012257057735.83
97 rdf:rest Nfb3f019749204420b422fc7f11184580
98 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
99 schema:name Engineering
100 rdf:type schema:DefinedTerm
101 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
102 schema:name Chemical Engineering
103 rdf:type schema:DefinedTerm
104 sg:journal.1136087 schema:issn 0965-5441
105 1555-6239
106 schema:name Petroleum Chemistry
107 schema:publisher Pleiades Publishing
108 rdf:type schema:Periodical
109 sg:person.010050175211.51 schema:affiliation grid-institutes:grid.448924.7
110 schema:familyName Chernysheva
111 schema:givenName E. A.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010050175211.51
113 rdf:type schema:Person
114 sg:person.010334416261.46 schema:affiliation grid-institutes:grid.423490.8
115 schema:familyName Magomadov
116 schema:givenName E. E.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010334416261.46
118 rdf:type schema:Person
119 sg:person.010431675375.32 schema:affiliation grid-institutes:grid.423490.8
120 schema:familyName Kadieva
121 schema:givenName M. Kh.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010431675375.32
123 rdf:type schema:Person
124 sg:person.011144042727.38 schema:affiliation grid-institutes:grid.448924.7
125 schema:familyName Zaytseva
126 schema:givenName O. V.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011144042727.38
128 rdf:type schema:Person
129 sg:person.012257057735.83 schema:affiliation grid-institutes:grid.423490.8
130 schema:familyName Batov
131 schema:givenName A. E.
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012257057735.83
133 rdf:type schema:Person
134 sg:person.012531050145.44 schema:affiliation grid-institutes:grid.423490.8
135 schema:familyName Kadiev
136 schema:givenName Kh. M.
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012531050145.44
138 rdf:type schema:Person
139 sg:person.01332170507.75 schema:affiliation grid-institutes:grid.423490.8
140 schema:familyName Khadzhiev
141 schema:givenName S. N.
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01332170507.75
143 rdf:type schema:Person
144 sg:person.013334364327.36 schema:affiliation grid-institutes:None
145 schema:familyName Oknina
146 schema:givenName N. V.
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013334364327.36
148 rdf:type schema:Person
149 sg:person.015361631601.61 schema:affiliation grid-institutes:grid.448924.7
150 schema:familyName Kapustin
151 schema:givenName V. M.
152 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015361631601.61
153 rdf:type schema:Person
154 sg:pub.10.1134/s0965544111010051 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028976970
155 https://doi.org/10.1134/s0965544111010051
156 rdf:type schema:CreativeWork
157 sg:pub.10.1134/s0965544111010063 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005790346
158 https://doi.org/10.1134/s0965544111010063
159 rdf:type schema:CreativeWork
160 sg:pub.10.1134/s0965544111060077 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032326510
161 https://doi.org/10.1134/s0965544111060077
162 rdf:type schema:CreativeWork
163 sg:pub.10.1134/s0965544113050113 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004135902
164 https://doi.org/10.1134/s0965544113050113
165 rdf:type schema:CreativeWork
166 grid-institutes:None schema:alternateName Electrogorsk Institute of Petroleum Processing, Electrogorsk, Moscow oblast, Russia
167 schema:name Electrogorsk Institute of Petroleum Processing, Electrogorsk, Moscow oblast, Russia
168 rdf:type schema:Organization
169 grid-institutes:grid.423490.8 schema:alternateName Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
170 schema:name Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
171 rdf:type schema:Organization
172 grid-institutes:grid.448924.7 schema:alternateName Gubkin Russian State University of Oil and Gas, Moscow, Russia
173 schema:name Gubkin Russian State University of Oil and Gas, Moscow, Russia
174 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
175 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...