The catalytic properties of transition metal sulfides synthesized from Anderson-type heteropoly compounds in hydrogenation, hydrodesulfurization, and hydrodenitrogenation reactions View Full Text


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Article Info

DATE

2013-07-13

AUTHORS

V. A. Sal’nikov, P. A. Nikul’shin, A. A. Pimerzin

ABSTRACT

XMo6HPC/Al2O3 catalysts based on Anderson-type heteropoly compounds (HPCs) with heteroatoms X = Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, and Al were synthesized. The catalytic properties of the prepared samples were studied in naphthalene hydrogenation, dibenzothiophene hydrodesulfurization, and quinoline hydrodenitrogenation. The highest activity was exhibited by the catalysts with X = Co and Ni; the lowest, with X = Cu. It was found that dibenzothiophene hydrodesulfurization and naphthalene hydrogenation occur on different active sites, whereas the sites of the hydrogenation of naphthalene and dibenzothiophene have a similar nature. Quinoline (at a nitrogen content of 100 ppm) had a different effect on the catalytic properties: it inhibited the hydrogenation of dibenzothiophene and naphthalene, but promoted the desulfurization of dibenzothiophene. More... »

PAGES

233-244

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544113040129

DOI

http://dx.doi.org/10.1134/s0965544113040129

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047015815


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