Fischer-Tropsch synthesis in a slurry reactor in the presence of nanosized cobalt catalysts synthesized in situ in a hydrocarbon medium View Full Text


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Article Info

DATE

2013-05-17

AUTHORS

S. N. Khadzhiev, A. Yu. Krylova, M. V. Kulikova, A. S. Lyadov, S. A. Sagitov

ABSTRACT

Fischer-Tropsch synthesis in a slurry reactor at a pressure of 20 atm and a temperature of 220–300°C in the presence of 100Co : 2Pd : (5–50)Al2O3 and 100Co : 2Pd : (20–50)ZrO2 (parts by weight) catalysts in situ synthesized in a hydrocarbon medium has been studied. The catalysts were prepared by the decomposition of cobalt salts and promoters in melted petroleum paraffin P-2 at 300°C and in situ reduced with hydrogen. It has been found that the nanocatalyst containing 20 parts by weight of ZrO2 exhibits the highest activity in the Fischer-Tropsch synthesis and provides the yield of liquid products of 70 g/m3 at a CO conversion of 80%. More... »

PAGES

152-156

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544113030031

DOI

http://dx.doi.org/10.1134/s0965544113030031

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007022026


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