Conversion of α-methylstyrene over pentasil zeolites with various silica ratios View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-09

AUTHORS

N. G. Grigor’eva, R. R. Galyautdinova, A. V. Vosmerikov, L. L. Korobitsina, B. I. Kutepov, U. M. Dzhemilev

ABSTRACT

It has been shown that α-methylstyrene in the presence of H-HSZ (SiO2/Al2O3 = 40–120) and Fe-HSZ (SiO2/Al2O3 = 60) pentasils in a nitrogen atmosphere (80–120°C, 5–20 wt % catalyst) is converted into linear (4-methyl-2,4-diphenylpent-1-and-2-enes) and cyclic (1,1,3-trimethyl-3-phenylindan) dimers. The H-type high-silica (SiO2/Al2O3 = 120) and ferrosilicate zeolites in air facilitate the conversion of α-methylstyrene into acetophenone and α-phenylpropionaldehyde. More... »

PAGES

366-370

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s096554410805006x

DOI

http://dx.doi.org/10.1134/s096554410805006x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006655196


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