Catalytic activity in hydrocarbon conversion of pentasil containing platinum, nickel, iron, or zinc nanoparticles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-05

AUTHORS

L. M. Velichkina, A. N. Pestryakov, A. V. Vosmerikov, I. V. Tuzovskaya, N. E. Bogdanchikova, M. Avalos, M. Farias, H. Tiznado

ABSTRACT

Catalyst samples containing nanosized Pt, Ni, Fe, or Zn powder were prepared on the basis of high-silica zeolite ZSM-5 by mechanical mixing. The structure and state of active centers of zeolite catalysts (freshly prepared or calcined after the reaction cycle of upgrading the petroleum straight-run gasoline fraction) were studied by means of the X-ray diffraction, UV spectroscopy, and X-ray photoelectron spectroscopy techniques. It was shown that the oxidized forms of the metals are practically absent from the freshly prepared zeolite samples. After the heat treatment of the catalysts in air, nanosized metal powders transform into oxides on the zeolite surface, with iron and nickel producing the greatest variety of oxidized forms. More... »

PAGES

201-205

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0965544108030055

DOI

http://dx.doi.org/10.1134/s0965544108030055

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015604672


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