Ontology type: schema:ScholarlyArticle
2013-07
AUTHORS ABSTRACTMutual interaction of redox pairs was evaluated using the concept of intrinsic oxygen fugacity in a melt. A “rose of trends” was proposed for the visualization of possible directions of mutual oxidation/reduction of redox pairs for a given melt composition. Missing thermodynamic data were estimated for vanadium redox pairs in sodium disilicate melt, and the V5+/V4+/V3+/V2+ tetrad was quantitatively described. The redistribution of vanadium in different valence states was estimated during quenching to glass of model iron-free and natural iron-bearing melts. More... »
PAGES305-315
http://scigraph.springernature.com/pub.10.1134/s0869591113040036
DOIhttp://dx.doi.org/10.1134/s0869591113040036
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