Mutual interaction of redox pairs in silicate melts: V5+/V4+/V3+/V2+ tetrad and other equilibria View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-07

AUTHORS

A. A. Borisov

ABSTRACT

Mutual interaction of redox pairs was evaluated using the concept of intrinsic oxygen fugacity in a melt. A “rose of trends” was proposed for the visualization of possible directions of mutual oxidation/reduction of redox pairs for a given melt composition. Missing thermodynamic data were estimated for vanadium redox pairs in sodium disilicate melt, and the V5+/V4+/V3+/V2+ tetrad was quantitatively described. The redistribution of vanadium in different valence states was estimated during quenching to glass of model iron-free and natural iron-bearing melts. More... »

PAGES

305-315

References to SciGraph publications

Journal

TITLE

Petrology

ISSUE

4

VOLUME

21

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0869591113040036

DOI

http://dx.doi.org/10.1134/s0869591113040036

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025473704


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