Ferrimagnetic Nature of Composite Products Based on 1,1'-Diacetylferrocene, ε-Caprolactam, and Taurine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-10-03

AUTHORS

V. N. Babin, Yu. A. Belousov, Yu. A. Borisov, V. N. Kulikov, S. E. Mazina, E. Yu. Rogatkina, A. N. Rodionov, A. A. Simenel, I. V. Shchetinin

ABSTRACT

Nuclear gamma resonance (NGR) is used to study powders of externally homogeneous magnetite-like substances that form in the reaction between 1,1'-diacetylferrocene and ε-caprolactam or 2-aminoethanesulfonic acid in a relatively low range of temperatures (100–180°C). The powders are shown to consist of magnetite and a ferrocene-containing matrix that contains 1,1'-diacetyleferrocene and an organic nitrogen-containing component. In studying the temperature dependence of the NGR spectra in the range of 295–80 K, it is established that a fast effective exchange of electrons occurs in the samples both internally and between two Fe2+/Fe3+ subsystems, ferrocene/ferricenium and sublattice B of magnetite. As a result, classical mechanisms of electron exchange retardation and the phase ordering of the magnetite structure do not work, and no Verwey transition is observed in the samples. More... »

PAGES

1989-1995

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024420100040

DOI

http://dx.doi.org/10.1134/s0036024420100040

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1131418510


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179 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
180 rdf:type schema:Organization
181 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
182 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
183 rdf:type schema:Organization
 




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