Spectral Luminescence Properties and Stability of Zinc(II) Dipyrromethenates with Different Structures in Proton-Donor Media in the Ground and Excited Electronic ... View Full Text


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Article Info

DATE

2019-02

AUTHORS

A. A. Prokopenko, R. T. Kuznetsova, Iu. V. Aksenova, E. N. Telminov, M. B. Berezin, E. V. Antina

ABSTRACT

The spectral luminescent properties of a series of zinc dipyrromethenate [Zn(dpm)2] with alkyl-, phenyl-, meso-aza-, and halogen substituents in the ligand are studied in solutions in ethanol (neutral and acidified with hydrochloric acid). The stability of the complexes in proton-donor solvents in the ground and excited states is investigated, and quantum yields of laser-induced phototransformations are measured. In a number of cases, a relationship between the photochemical stability of the investigated dipyrromethenates and their properties in proton-donor media is found and discussed. More... »

PAGES

301-307

References to SciGraph publications

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  • 2012-09-29. Kinetics of the dissociation of zinc(II) complexes with 3,3′-bis(dipyrrolylmethenes) in acetic acid-benzene binary solvent in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • 2016-01-07. Stabilities of a series of dipyrrin difluoroborates in protic solvents in the ground and electron-excited states in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • 2012-05-24. Spectral, luminescent, photochemical, and laser properties of a series of boron fluoride complexes of dipyrrolylmethenes in solutions in OPTICS AND SPECTROSCOPY
  • 2012-07. Synthesis and properties of (1,2,3,7,9-pentamethyldipyrrolylmethen-8-yl)-(1,2,3,7,8-pentamethyldipyrrolylmethen-9-yl)methane and bis(1,2,3,7,9-pentamethyldipyrrolylmethen-8-yl)trifluoromethylmethane dihydrobromides in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2014-02-26. Synthesis, Spectral-Luminescent Properties, and Photostability of Zn(II) Complexes With Dipyrrins Modified by the Periphery and meso-Spacer in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 2014-12-24. Photonics of zinc(II) and boron(III) chelates with methyl- and phenyl-substituted dipyrromethenes and azadipyrromethenes in HIGH ENERGY CHEMISTRY
  • 2010-08-26. Synthesis, stability in solutions, and spectral and thermal properties of alkyl-substituted 3,3′-bis(dipyrromethene) hydrobromides in RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • 2010-06-01. Synthesis and optical properties of BF2-complexes of alkylated dipyrrolylmethenes (BODIPY) in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
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    http://scigraph.springernature.com/pub.10.1134/s0036024419010229

    DOI

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    DIMENSIONS

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