Kinetics and mechanism of the catalytic reaction between alcohols and dimethyl carbonate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-03

AUTHORS

K. F. Koledina, S. N. Koledin, N. A. Shchadneva, I. M. Gubaidullin

ABSTRACT

The mechanism of the reaction between alcohols and dimethyl carbonate, catalyzed by dicobalt octacarbonyl Co2(CO)8, is studied by means of mathematical modeling. Kinetic models for possible schemes of chemical transformations are constructed at different initial concentrations of the catalyst. Based on a comparative analysis of activation energies of possible stages of chemical transformations, possible reaction pathways are determined and an appropriate mechanism is selected. More... »

PAGES

442-447

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602441703013x

DOI

http://dx.doi.org/10.1134/s003602441703013x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084222965


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Ufa State Petroleum Technological University", 
          "id": "https://www.grid.ac/institutes/grid.446213.6", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450077, Ufa, Russia", 
            "Ufa State Oil Technical University, 450000, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Koledina", 
        "givenName": "K. F.", 
        "id": "sg:person.013342367567.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013342367567.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ufa State Petroleum Technological University", 
          "id": "https://www.grid.ac/institutes/grid.446213.6", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450077, Ufa, Russia", 
            "Ufa State Oil Technical University, 450000, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Koledin", 
        "givenName": "S. N.", 
        "id": "sg:person.012361232442.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012361232442.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450077, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shchadneva", 
        "givenName": "N. A.", 
        "id": "sg:person.016242662471.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016242662471.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ufa State Petroleum Technological University", 
          "id": "https://www.grid.ac/institutes/grid.446213.6", 
          "name": [
            "Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450077, Ufa, Russia", 
            "Ufa State Oil Technical University, 450000, Ufa, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gubaidullin", 
        "givenName": "I. M.", 
        "id": "sg:person.07671552071.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07671552071.65"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0965542506080057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004421636", 
          "https://doi.org/10.1134/s0965542506080057"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11144-015-0876-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026817951", 
          "https://doi.org/10.1007/s11144-015-0876-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036024416050186", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033632722", 
          "https://doi.org/10.1134/s0036024416050186"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428014060050", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043588108", 
          "https://doi.org/10.1134/s1070428014060050"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01125a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055770920"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.4186/ej.2014.18.1.13", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1072348019"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.5155/eurjchem.3.3.367-394.604", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1072641540"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-03", 
    "datePublishedReg": "2017-03-01", 
    "description": "The mechanism of the reaction between alcohols and dimethyl carbonate, catalyzed by dicobalt octacarbonyl Co2(CO)8, is studied by means of mathematical modeling. Kinetic models for possible schemes of chemical transformations are constructed at different initial concentrations of the catalyst. Based on a comparative analysis of activation energies of possible stages of chemical transformations, possible reaction pathways are determined and an appropriate mechanism is selected.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s003602441703013x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1327871", 
        "issn": [
          "0036-0244", 
          "0044-4537"
        ], 
        "name": "Russian Journal of Physical Chemistry A", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "91"
      }
    ], 
    "name": "Kinetics and mechanism of the catalytic reaction between alcohols and dimethyl carbonate", 
    "pagination": "442-447", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f1719245fc8d80fe5f239f0db237a1b11f3fecaa7b74a73a8300f9a71f329ec4"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s003602441703013x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1084222965"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s003602441703013x", 
      "https://app.dimensions.ai/details/publication/pub.1084222965"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000484.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S003602441703013X"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s003602441703013x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s003602441703013x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s003602441703013x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s003602441703013x'


 

This table displays all metadata directly associated to this object as RDF triples.

111 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s003602441703013x schema:about anzsrc-for:03
2 anzsrc-for:0399
3 schema:author Ndf8330a20db7411f83b5660ffa23ec73
4 schema:citation sg:pub.10.1007/s11144-015-0876-6
5 sg:pub.10.1134/s0036024416050186
6 sg:pub.10.1134/s0965542506080057
7 sg:pub.10.1134/s1070428014060050
8 https://doi.org/10.1021/ja01125a023
9 https://doi.org/10.4186/ej.2014.18.1.13
10 https://doi.org/10.5155/eurjchem.3.3.367-394.604
11 schema:datePublished 2017-03
12 schema:datePublishedReg 2017-03-01
13 schema:description The mechanism of the reaction between alcohols and dimethyl carbonate, catalyzed by dicobalt octacarbonyl Co2(CO)8, is studied by means of mathematical modeling. Kinetic models for possible schemes of chemical transformations are constructed at different initial concentrations of the catalyst. Based on a comparative analysis of activation energies of possible stages of chemical transformations, possible reaction pathways are determined and an appropriate mechanism is selected.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf Nb50631e537134540a47349dfd0bbb2c8
18 Nc3b3cef1dc234c6bb5acdc5c83654a33
19 sg:journal.1327871
20 schema:name Kinetics and mechanism of the catalytic reaction between alcohols and dimethyl carbonate
21 schema:pagination 442-447
22 schema:productId N407873da02824b778b2e04219ad5efc1
23 N4678a43493bc4710ab39b5a7596d267f
24 N9849402f05ef42f988bc588fa87315cf
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084222965
26 https://doi.org/10.1134/s003602441703013x
27 schema:sdDatePublished 2019-04-10T14:54
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher N2125741f907249d48d2df76d5969b906
30 schema:url http://link.springer.com/10.1134/S003602441703013X
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N0165f9ee43674d66a2b5a4cc7236ea07 rdf:first sg:person.016242662471.03
35 rdf:rest N984d61f456ec4584bf0bf7a8412ad755
36 N2125741f907249d48d2df76d5969b906 schema:name Springer Nature - SN SciGraph project
37 rdf:type schema:Organization
38 N407873da02824b778b2e04219ad5efc1 schema:name readcube_id
39 schema:value f1719245fc8d80fe5f239f0db237a1b11f3fecaa7b74a73a8300f9a71f329ec4
40 rdf:type schema:PropertyValue
41 N4678a43493bc4710ab39b5a7596d267f schema:name dimensions_id
42 schema:value pub.1084222965
43 rdf:type schema:PropertyValue
44 N9849402f05ef42f988bc588fa87315cf schema:name doi
45 schema:value 10.1134/s003602441703013x
46 rdf:type schema:PropertyValue
47 N984d61f456ec4584bf0bf7a8412ad755 rdf:first sg:person.07671552071.65
48 rdf:rest rdf:nil
49 Nb1f88bd8349e4054bc69e573fcc98a07 rdf:first sg:person.012361232442.37
50 rdf:rest N0165f9ee43674d66a2b5a4cc7236ea07
51 Nb50631e537134540a47349dfd0bbb2c8 schema:issueNumber 3
52 rdf:type schema:PublicationIssue
53 Nc3b3cef1dc234c6bb5acdc5c83654a33 schema:volumeNumber 91
54 rdf:type schema:PublicationVolume
55 Ndf8330a20db7411f83b5660ffa23ec73 rdf:first sg:person.013342367567.07
56 rdf:rest Nb1f88bd8349e4054bc69e573fcc98a07
57 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
58 schema:name Chemical Sciences
59 rdf:type schema:DefinedTerm
60 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
61 schema:name Other Chemical Sciences
62 rdf:type schema:DefinedTerm
63 sg:journal.1327871 schema:issn 0036-0244
64 0044-4537
65 schema:name Russian Journal of Physical Chemistry A
66 rdf:type schema:Periodical
67 sg:person.012361232442.37 schema:affiliation https://www.grid.ac/institutes/grid.446213.6
68 schema:familyName Koledin
69 schema:givenName S. N.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012361232442.37
71 rdf:type schema:Person
72 sg:person.013342367567.07 schema:affiliation https://www.grid.ac/institutes/grid.446213.6
73 schema:familyName Koledina
74 schema:givenName K. F.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013342367567.07
76 rdf:type schema:Person
77 sg:person.016242662471.03 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
78 schema:familyName Shchadneva
79 schema:givenName N. A.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016242662471.03
81 rdf:type schema:Person
82 sg:person.07671552071.65 schema:affiliation https://www.grid.ac/institutes/grid.446213.6
83 schema:familyName Gubaidullin
84 schema:givenName I. M.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07671552071.65
86 rdf:type schema:Person
87 sg:pub.10.1007/s11144-015-0876-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026817951
88 https://doi.org/10.1007/s11144-015-0876-6
89 rdf:type schema:CreativeWork
90 sg:pub.10.1134/s0036024416050186 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033632722
91 https://doi.org/10.1134/s0036024416050186
92 rdf:type schema:CreativeWork
93 sg:pub.10.1134/s0965542506080057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004421636
94 https://doi.org/10.1134/s0965542506080057
95 rdf:type schema:CreativeWork
96 sg:pub.10.1134/s1070428014060050 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043588108
97 https://doi.org/10.1134/s1070428014060050
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1021/ja01125a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055770920
100 rdf:type schema:CreativeWork
101 https://doi.org/10.4186/ej.2014.18.1.13 schema:sameAs https://app.dimensions.ai/details/publication/pub.1072348019
102 rdf:type schema:CreativeWork
103 https://doi.org/10.5155/eurjchem.3.3.367-394.604 schema:sameAs https://app.dimensions.ai/details/publication/pub.1072641540
104 rdf:type schema:CreativeWork
105 https://www.grid.ac/institutes/grid.446213.6 schema:alternateName Ufa State Petroleum Technological University
106 schema:name Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450077, Ufa, Russia
107 Ufa State Oil Technical University, 450000, Ufa, Russia
108 rdf:type schema:Organization
109 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
110 schema:name Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450077, Ufa, Russia
111 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...