The Role of Structure and Conductivity of Perovskites Bi4V2−2xM2xO11−δ (M = Cu2+, Fe3+, Zr4+) in the Catalytic Dehydrogenation of Isobutanol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-04

AUTHORS

I. I. Mikhalenko, E. I. Povarova, A. I. Pylinina

ABSTRACT

The catalytic activity of solid electrolytes from the family of complex bismuth vanadates Bi4V2−2xM2xO11−δ (BIMEVOX) with V5+ ions partially substituted by 3d metal cations was studied. In the transformations of isobutanol, it was found to depend on the crystal structure (α, β, γ Aurivillius phases), which changes at increased dopant ion contents (xM). The highly conductive tetragonal γ phase was most active for all BIMEVOX oxides. The activation energy of the dehydrogenation of isobutanol EaC=O increased linearly with the charge of the Mn+ ion and activation energy of conductivity of the γ phase of BIMEVOX in the series Cu2+ → Fe3+ → Zr4+. More... »

PAGES

771-776

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024416040221

DOI

http://dx.doi.org/10.1134/s0036024416040221

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001027950


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