Kinetics and mechanism of N-chloromethylamine decomposition in solutions View Full Text


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Article Info

DATE

2016-02-19

AUTHORS

V. V. Kuznetsov, M. D. Vedenyapina, M. I. Pleshchev, S. B. Gashev, N. N. Makhova, A. A. Vedenyapin

ABSTRACT

Kinetics of N-chloromethylamine decomposition in an aqueous base medium and chloroform at different temperatures is studied. The decomposition of N-chloromethylamine is found to obey a second order equation in an aqueous base medium at an equimolar ratio of the reagents and a first order equation in chloroform with excess base. The activation energy of N-chloromethylamine decomposition in the both solvents is determined. A mechanism for the reaction is proposed. N-Chloromethylamine is shown to have approximately equal stability in these solvents within the studied temperature range. More... »

PAGES

541-544

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024416030225

DOI

http://dx.doi.org/10.1134/s0036024416030225

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020874335


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