Influence of porogen nature on the kinetic and potential efficiencies of divinylbenzene-based monolithic sorbents in gas chromatography View Full Text


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Article Info

DATE

2014-12-30

AUTHORS

A. A. Korolev, V. E. Shiryaeva, T. P. Popova, A. Yu. Kanat’eva, A. A. Kurganov

ABSTRACT

It has been shown that using Poppe curves for characterization of monolithic sorbents makes it possible to optimize conditions for both the synthesis of monoliths intended for high-speed analysis and achievement of the best separation efficiency. The influence of the nature of a porogen on the kinetic efficiency of monolithic sorbents in high-pressure gas chromatography has been considered. It has been found that the nature of the porogen alcohol determines to a considerable extent the structure of the monolith and its kinetic efficiency. The sorbents prepared with the use of octanol-1 and dodecanol-1 have shown the best kinetic characteristics; however, minimal HETP values have been observed for the columns prepared using hexanol-1 as a porogen. More... »

PAGES

317-323

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024415020144

DOI

http://dx.doi.org/10.1134/s0036024415020144

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013808882


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