Chromatographic characteristics of monolithic capillary columns with different polarities View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-08-05

AUTHORS

A. A. Korolev, V. E. Shiryaeva, T. P. Popova, A. A. Kurganov

ABSTRACT

Relative polarity values and retention indices for a mixture of normal paraffins C5–C10 and alkylbezenes C6–C9 are determined for four types of monolithic capillary columns based on divinylbenzene, ethylene glycol dimethacrylate, pentaerythritol tetraacrylate, and pentaerythritol triacrylate. It is established that the retention of polar sorbates increases with a rise in stationary phase polarity, while the retention of nonpolar compounds grows with a reduction in stationary phase polarity. More... »

PAGES

1609-1612

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024414090209

DOI

http://dx.doi.org/10.1134/s0036024414090209

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025470858


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0301", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Analytical Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korolev", 
        "givenName": "A. A.", 
        "id": "sg:person.0761776377.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0761776377.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shiryaeva", 
        "givenName": "V. E.", 
        "id": "sg:person.01055573762.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01055573762.38"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Popova", 
        "givenName": "T. P.", 
        "id": "sg:person.01123707162.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01123707162.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.423490.8", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kurganov", 
        "givenName": "A. A.", 
        "id": "sg:person.01240135562.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01240135562.44"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0036024407030259", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014044385", 
          "https://doi.org/10.1134/s0036024407030259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00448575", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050256937", 
          "https://doi.org/10.1007/bf00448575"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036024409070292", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044118699", 
          "https://doi.org/10.1134/s0036024409070292"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-08-05", 
    "datePublishedReg": "2014-08-05", 
    "description": "Relative polarity values and retention indices for a mixture of normal paraffins C5\u2013C10 and alkylbezenes C6\u2013C9 are determined for four types of monolithic capillary columns based on divinylbenzene, ethylene glycol dimethacrylate, pentaerythritol tetraacrylate, and pentaerythritol triacrylate. It is established that the retention of polar sorbates increases with a rise in stationary phase polarity, while the retention of nonpolar compounds grows with a reduction in stationary phase polarity.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s0036024414090209", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1327871", 
        "issn": [
          "0036-0244", 
          "0044-4537"
        ], 
        "name": "Russian Journal of Physical Chemistry A", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "88"
      }
    ], 
    "keywords": [
      "ethylene glycol dimethacrylate", 
      "monolithic capillary columns", 
      "glycol dimethacrylate", 
      "phase polarity", 
      "capillary column", 
      "pentaerythritol tetraacrylate", 
      "polar sorbates", 
      "nonpolar compounds", 
      "column", 
      "dimethacrylate", 
      "stationary phase polarity", 
      "mixture", 
      "divinylbenzene", 
      "tetraacrylate", 
      "pentaerythritol", 
      "different polarity", 
      "retention", 
      "polarity", 
      "characteristics", 
      "values", 
      "sorbate", 
      "reduction", 
      "types", 
      "rise", 
      "chromatographic characteristics", 
      "polarity values", 
      "C6-C9", 
      "compounds", 
      "index", 
      "retention indices", 
      "C5\u2013C10", 
      "Relative polarity values", 
      "normal paraffins C5\u2013C10", 
      "paraffins C5\u2013C10", 
      "alkylbezenes C6\u2013C9"
    ], 
    "name": "Chromatographic characteristics of monolithic capillary columns with different polarities", 
    "pagination": "1609-1612", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1025470858"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036024414090209"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036024414090209", 
      "https://app.dimensions.ai/details/publication/pub.1025470858"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:22", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_623.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s0036024414090209"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036024414090209'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036024414090209'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036024414090209'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036024414090209'


 

This table displays all metadata directly associated to this object as RDF triples.

126 TRIPLES      22 PREDICATES      63 URIs      52 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036024414090209 schema:about anzsrc-for:03
2 anzsrc-for:0301
3 schema:author Na9619cefebf843428a4842cb26f33bcf
4 schema:citation sg:pub.10.1007/bf00448575
5 sg:pub.10.1134/s0036024407030259
6 sg:pub.10.1134/s0036024409070292
7 schema:datePublished 2014-08-05
8 schema:datePublishedReg 2014-08-05
9 schema:description Relative polarity values and retention indices for a mixture of normal paraffins C5–C10 and alkylbezenes C6–C9 are determined for four types of monolithic capillary columns based on divinylbenzene, ethylene glycol dimethacrylate, pentaerythritol tetraacrylate, and pentaerythritol triacrylate. It is established that the retention of polar sorbates increases with a rise in stationary phase polarity, while the retention of nonpolar compounds grows with a reduction in stationary phase polarity.
10 schema:genre article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N01c5e562ae2a483b835d70f216c58a96
14 Nd434c677f75d4e02853e6185fd924cb9
15 sg:journal.1327871
16 schema:keywords C5–C10
17 C6-C9
18 Relative polarity values
19 alkylbezenes C6–C9
20 capillary column
21 characteristics
22 chromatographic characteristics
23 column
24 compounds
25 different polarity
26 dimethacrylate
27 divinylbenzene
28 ethylene glycol dimethacrylate
29 glycol dimethacrylate
30 index
31 mixture
32 monolithic capillary columns
33 nonpolar compounds
34 normal paraffins C5–C10
35 paraffins C5–C10
36 pentaerythritol
37 pentaerythritol tetraacrylate
38 phase polarity
39 polar sorbates
40 polarity
41 polarity values
42 reduction
43 retention
44 retention indices
45 rise
46 sorbate
47 stationary phase polarity
48 tetraacrylate
49 types
50 values
51 schema:name Chromatographic characteristics of monolithic capillary columns with different polarities
52 schema:pagination 1609-1612
53 schema:productId N4d88e72f9a374918a954867c9ae47f45
54 Nab2cacc17e4a4fe0b9bff021fca0f8e7
55 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025470858
56 https://doi.org/10.1134/s0036024414090209
57 schema:sdDatePublished 2021-11-01T18:22
58 schema:sdLicense https://scigraph.springernature.com/explorer/license/
59 schema:sdPublisher N81e891ea5dae407298d09b8e4b780bfd
60 schema:url https://doi.org/10.1134/s0036024414090209
61 sgo:license sg:explorer/license/
62 sgo:sdDataset articles
63 rdf:type schema:ScholarlyArticle
64 N01c5e562ae2a483b835d70f216c58a96 schema:issueNumber 9
65 rdf:type schema:PublicationIssue
66 N4d88e72f9a374918a954867c9ae47f45 schema:name dimensions_id
67 schema:value pub.1025470858
68 rdf:type schema:PropertyValue
69 N81e891ea5dae407298d09b8e4b780bfd schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 N9ed2dd06871b42649cca74b542acdd70 rdf:first sg:person.01240135562.44
72 rdf:rest rdf:nil
73 Na9619cefebf843428a4842cb26f33bcf rdf:first sg:person.0761776377.67
74 rdf:rest Naf7ebbbb6099489785203e7e5b942308
75 Nab2cacc17e4a4fe0b9bff021fca0f8e7 schema:name doi
76 schema:value 10.1134/s0036024414090209
77 rdf:type schema:PropertyValue
78 Naf7ebbbb6099489785203e7e5b942308 rdf:first sg:person.01055573762.38
79 rdf:rest Nb015b0a33de247c5a5f2f2121599fc1b
80 Nb015b0a33de247c5a5f2f2121599fc1b rdf:first sg:person.01123707162.15
81 rdf:rest N9ed2dd06871b42649cca74b542acdd70
82 Nd434c677f75d4e02853e6185fd924cb9 schema:volumeNumber 88
83 rdf:type schema:PublicationVolume
84 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
85 schema:name Chemical Sciences
86 rdf:type schema:DefinedTerm
87 anzsrc-for:0301 schema:inDefinedTermSet anzsrc-for:
88 schema:name Analytical Chemistry
89 rdf:type schema:DefinedTerm
90 sg:journal.1327871 schema:issn 0036-0244
91 0044-4537
92 schema:name Russian Journal of Physical Chemistry A
93 schema:publisher Pleiades Publishing
94 rdf:type schema:Periodical
95 sg:person.01055573762.38 schema:affiliation grid-institutes:grid.423490.8
96 schema:familyName Shiryaeva
97 schema:givenName V. E.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01055573762.38
99 rdf:type schema:Person
100 sg:person.01123707162.15 schema:affiliation grid-institutes:grid.423490.8
101 schema:familyName Popova
102 schema:givenName T. P.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01123707162.15
104 rdf:type schema:Person
105 sg:person.01240135562.44 schema:affiliation grid-institutes:grid.423490.8
106 schema:familyName Kurganov
107 schema:givenName A. A.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01240135562.44
109 rdf:type schema:Person
110 sg:person.0761776377.67 schema:affiliation grid-institutes:grid.423490.8
111 schema:familyName Korolev
112 schema:givenName A. A.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0761776377.67
114 rdf:type schema:Person
115 sg:pub.10.1007/bf00448575 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050256937
116 https://doi.org/10.1007/bf00448575
117 rdf:type schema:CreativeWork
118 sg:pub.10.1134/s0036024407030259 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014044385
119 https://doi.org/10.1134/s0036024407030259
120 rdf:type schema:CreativeWork
121 sg:pub.10.1134/s0036024409070292 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044118699
122 https://doi.org/10.1134/s0036024409070292
123 rdf:type schema:CreativeWork
124 grid-institutes:grid.423490.8 schema:alternateName Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia
125 schema:name Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 117912, Moscow, Russia
126 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...