Ontology type: schema:ScholarlyArticle
2014-03-15
AUTHORSB. R. Saifutdinov, V. A. Davankov, M. M. Il’in
ABSTRACTThe sorption of a series of aromatic heterocycles on neutral hypercrosslinked polystyrene from maximally dilute acetonitrile and water.acetonitrile solutions of them is investigated by high-performance liquid chromatography in a range of column temperatures from 308 to 348 K at 5 K intervals. It is found that for all heterocycles, the logarithm of the retention factor versus the reciprocal of the temperature dependences can be approximated by linear functions with r2 ≥ 0.999. It is established that the true compensation effect (which does not result from the correlation between enthalpy and entropy determination errors) occurs during the sorption of heterocycles on hypercrosslinked polystyrene from both acetonitrile and water-acetonitrile solutions. It is shown that in the compensation diagram, the points corresponding to sorbates are grouped together according to the type of sorbate-sorbent interactions. It is found that changes in the Gibbs energy, enthalpy, and entropy of sorption from acetonitrile solutions and for sorption from water-acetonitrile solutions are related to one another by linear dependences. More... »
PAGES358-364
http://scigraph.springernature.com/pub.10.1134/s0036024414030224
DOIhttp://dx.doi.org/10.1134/s0036024414030224
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1036028161
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Samara State Technical University, 443100, Samara, Russia",
"id": "http://www.grid.ac/institutes/grid.445792.9",
"name": [
"Samara State Technical University, 443100, Samara, Russia"
],
"type": "Organization"
},
"familyName": "Saifutdinov",
"givenName": "B. R.",
"id": "sg:person.012400111300.06",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012400111300.06"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.431939.5",
"name": [
"Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Davankov",
"givenName": "V. A.",
"id": "sg:person.01017203757.66",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01017203757.66"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia",
"id": "http://www.grid.ac/institutes/grid.431939.5",
"name": [
"Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Il\u2019in",
"givenName": "M. M.",
"id": "sg:person.015661113163.01",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015661113163.01"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1134/s003602441009027x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011030948",
"https://doi.org/10.1134/s003602441009027x"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02493669",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050738337",
"https://doi.org/10.1007/bf02493669"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/261566a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034526878",
"https://doi.org/10.1038/261566a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036024410100146",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000766475",
"https://doi.org/10.1134/s0036024410100146"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036024411070314",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012476831",
"https://doi.org/10.1134/s0036024411070314"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036024411010122",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015853842",
"https://doi.org/10.1134/s0036024411010122"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1811238209010135",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047597902",
"https://doi.org/10.1134/s1811238209010135"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036024413040250",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018260006",
"https://doi.org/10.1134/s0036024413040250"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036024413030266",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011001353",
"https://doi.org/10.1134/s0036024413030266"
],
"type": "CreativeWork"
}
],
"datePublished": "2014-03-15",
"datePublishedReg": "2014-03-15",
"description": "The sorption of a series of aromatic heterocycles on neutral hypercrosslinked polystyrene from maximally dilute acetonitrile and water.acetonitrile solutions of them is investigated by high-performance liquid chromatography in a range of column temperatures from 308 to 348 K at 5 K intervals. It is found that for all heterocycles, the logarithm of the retention factor versus the reciprocal of the temperature dependences can be approximated by linear functions with r2 \u2265 0.999. It is established that the true compensation effect (which does not result from the correlation between enthalpy and entropy determination errors) occurs during the sorption of heterocycles on hypercrosslinked polystyrene from both acetonitrile and water-acetonitrile solutions. It is shown that in the compensation diagram, the points corresponding to sorbates are grouped together according to the type of sorbate-sorbent interactions. It is found that changes in the Gibbs energy, enthalpy, and entropy of sorption from acetonitrile solutions and for sorption from water-acetonitrile solutions are related to one another by linear dependences.",
"genre": "article",
"id": "sg:pub.10.1134/s0036024414030224",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1327871",
"issn": [
"0036-0244",
"0044-4537"
],
"name": "Russian Journal of Physical Chemistry A",
"publisher": "Pleiades Publishing",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "88"
}
],
"keywords": [
"water-acetonitrile solutions",
"acetonitrile solution",
"sorbate-sorbent interactions",
"aromatic heterocycles",
"high-performance liquid chromatography",
"tetrazine derivatives",
"heterocycles",
"column temperature",
"retention factors",
"sorption",
"polystyrene",
"liquid chromatography",
"Gibbs energy",
"compensation diagram",
"linear dependence",
"acetonitrile",
"solution",
"compensation effect",
"chromatography",
"temperature dependence",
"enthalpy",
"derivatives",
"water",
"sorbate",
"thermodynamics",
"dependence",
"series",
"range",
"temperature",
"interaction",
"energy",
"logarithm",
"linear function",
"R2",
"diagram",
"effect",
"types",
"changes",
"one",
"function",
"point",
"factors",
"true compensation effect",
"intervals"
],
"name": "Thermodynamics of the sorption of 1,3,4-oxadiazole and 1,2,4,5-tetrazine derivatives from solutions on hypercrosslinked polystyrene",
"pagination": "358-364",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1036028161"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s0036024414030224"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s0036024414030224",
"https://app.dimensions.ai/details/publication/pub.1036028161"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:30",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_628.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1134/s0036024414030224"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036024414030224'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036024414030224'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036024414030224'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036024414030224'
This table displays all metadata directly associated to this object as RDF triples.
155 TRIPLES
22 PREDICATES
78 URIs
61 LITERALS
6 BLANK NODES