Combining monolithic and hollow capillary columns under conditions of two-dimensional gas chromatography View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

M. E. Dianov, A. A. Korolev, V. E. Shiryaeva, A. Yu. Kanat’eva, A. A. Kurganov

ABSTRACT

A monolithic column with the optimum structure of its monolithic layer is considered as a second dimension column under the conditions of two-dimensional gas chromatography. It is shown that despite the considerable difference between the working pressures of different columns, sample transfer from a hollow capillary column to a monolithic column is possible when a looped switching valve is used. It is found that the additional broadening of the chromatographic zone observed during sample transfer can be effectively suppressed by using an additional flow splitter. At the same time, reducing the volume of the switching valve loop is inefficient and does not allow effective separation by the monolithic column. More... »

PAGES

1374-1379

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024413080104

DOI

http://dx.doi.org/10.1134/s0036024413080104

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007776881


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