Features of the temperature dependence for the rates of gas-phase reactions of combustion View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

V. V. Azatyan

ABSTRACT

The specific character of the dependence for the rate of most gas-phase reactions of combustion on temperature and reagent concentrations is found to be determined by the ratio of the rates of the multiplication and death of active intermediate particles. It is shown that the stepwise acceleration of the process and the transition to the combustion mode upon raising the initial temperature by 1–2 K and crossing over a critical value is due to a change in the character of the rate’s temperature dependence as a result of the sign changing from negative to positive to reflect the difference between the rates of chain branching and termination. It is concluded that this difference’s change in sign upon varying the content of reagents imposes limits on concentration. More... »

PAGES

1295-1299

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024413070066

DOI

http://dx.doi.org/10.1134/s0036024413070066

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011380598


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