Mechanism of complexation of the phenothiazine dye methylene blue with fullerene C60 View Full Text


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Article Info

DATE

2013-04

AUTHORS

A. S. Buchelnikov, V. V. Kostyukov, M. P. Yevstigneev, Yu. I. Prylutskyy

ABSTRACT

The complexation of fullerene C60 with the aromatic dye methylene blue (MB) in aqueous solution was studied. Spectrophotometric titration revealed a reasonably strong interaction between C60 and MB molecules with an equilibrium constant K = 2110 L/mol and the binding of up to five dye molecules with the surface of C60. The energy analysis of the MB-C60 system showed that the intermolecular and hydrophobic interactions were dominant in the energy profile of the complexation, and while the electrostatic factor played an insignificant role. More... »

PAGES

662-667

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024413040067

DOI

http://dx.doi.org/10.1134/s0036024413040067

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007482323


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