Structure of bismuth(III) complexes with thiourea according to EXAFS spectroscopy Data View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-03

AUTHORS

S. B. Erenburg, S. V. Trubina, N. N. Golovnev

ABSTRACT

The EXAFS and XANES spectra of the solid complex Bi(tu)6(ClO4)3 (1) (tu is thiourea) and the solutions 0.1 M Bi(ClO4)3 + 1.8 M tu + 1 M HClO4 (2) and 0.05 M Bi(ClO4)3 + 1.5 M tu + 1 M HClO4 (3) were recorded. For solid [Bi(tu)6](ClO4)3, it was found that the first coordination shell of the Bi atom contains six sulfur atoms at distances of ∼2.7–2.9 Å. It was assumed that binuclear bismuth complexes with Bi-S distances of ∼2.8 and ∼3.3 Å formed in Bi(ClO4)3 + (tu) + HClO4 solutions. More... »

PAGES

461-464

References to SciGraph publications

  • 2012-04. Crystal structure of hexakis-(N-methylthiourea) bismuth(III) triperchlorate in RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s0036024413030102

    DOI

    http://dx.doi.org/10.1134/s0036024413030102

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1017660820


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
              "id": "https://www.grid.ac/institutes/grid.425759.8", 
              "name": [
                "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Erenburg", 
            "givenName": "S. B.", 
            "id": "sg:person.07704211421.42", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07704211421.42"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
              "id": "https://www.grid.ac/institutes/grid.425759.8", 
              "name": [
                "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Trubina", 
            "givenName": "S. V.", 
            "id": "sg:person.014374177255.13", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014374177255.13"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Siberian Federal University", 
              "id": "https://www.grid.ac/institutes/grid.412592.9", 
              "name": [
                "Siberian Federal University, Krasnoyarsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Golovnev", 
            "givenName": "N. N.", 
            "id": "sg:person.016134421043.54", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016134421043.54"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.2116/bunsekikagaku.29.11_785", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000469003"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.2116/bunsekikagaku.29.11_785", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1000469003"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0025-5408(01)00734-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011375229"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/cr980425s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013908869"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/cr980425s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1013908869"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.molliq.2004.07.015", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014344851"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0022-1902(66)80241-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038036334"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0022-1902(66)80241-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1038036334"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1139/v07-108", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1042190912"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1134/s0036023612040250", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1045742861", 
              "https://doi.org/10.1134/s0036023612040250"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/j.ccr.2007.03.003", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053018551"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic000022m", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055537444"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ic000022m", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055537444"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2013-03", 
        "datePublishedReg": "2013-03-01", 
        "description": "The EXAFS and XANES spectra of the solid complex Bi(tu)6(ClO4)3 (1) (tu is thiourea) and the solutions 0.1 M Bi(ClO4)3 + 1.8 M tu + 1 M HClO4 (2) and 0.05 M Bi(ClO4)3 + 1.5 M tu + 1 M HClO4 (3) were recorded. For solid [Bi(tu)6](ClO4)3, it was found that the first coordination shell of the Bi atom contains six sulfur atoms at distances of \u223c2.7\u20132.9 \u00c5. It was assumed that binuclear bismuth complexes with Bi-S distances of \u223c2.8 and \u223c3.3 \u00c5 formed in Bi(ClO4)3 + (tu) + HClO4 solutions.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1134/s0036024413030102", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1327871", 
            "issn": [
              "0036-0244", 
              "0044-4537"
            ], 
            "name": "Russian Journal of Physical Chemistry A", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "3", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "87"
          }
        ], 
        "name": "Structure of bismuth(III) complexes with thiourea according to EXAFS spectroscopy Data", 
        "pagination": "461-464", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "54253b6f6f6d9c8dc511a43a610d60f40d9a2199bf5761ab81a830c556cce9ee"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s0036024413030102"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1017660820"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s0036024413030102", 
          "https://app.dimensions.ai/details/publication/pub.1017660820"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T19:55", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000504.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1134/S0036024413030102"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036024413030102'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036024413030102'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036024413030102'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036024413030102'


     

    This table displays all metadata directly associated to this object as RDF triples.

    106 TRIPLES      21 PREDICATES      36 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s0036024413030102 schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 schema:author Ndc3ded39103b464e823a7812567235f4
    4 schema:citation sg:pub.10.1134/s0036023612040250
    5 https://doi.org/10.1016/0022-1902(66)80241-5
    6 https://doi.org/10.1016/j.ccr.2007.03.003
    7 https://doi.org/10.1016/j.molliq.2004.07.015
    8 https://doi.org/10.1016/s0025-5408(01)00734-6
    9 https://doi.org/10.1021/cr980425s
    10 https://doi.org/10.1021/ic000022m
    11 https://doi.org/10.1139/v07-108
    12 https://doi.org/10.2116/bunsekikagaku.29.11_785
    13 schema:datePublished 2013-03
    14 schema:datePublishedReg 2013-03-01
    15 schema:description The EXAFS and XANES spectra of the solid complex Bi(tu)6(ClO4)3 (1) (tu is thiourea) and the solutions 0.1 M Bi(ClO4)3 + 1.8 M tu + 1 M HClO4 (2) and 0.05 M Bi(ClO4)3 + 1.5 M tu + 1 M HClO4 (3) were recorded. For solid [Bi(tu)6](ClO4)3, it was found that the first coordination shell of the Bi atom contains six sulfur atoms at distances of ∼2.7–2.9 Å. It was assumed that binuclear bismuth complexes with Bi-S distances of ∼2.8 and ∼3.3 Å formed in Bi(ClO4)3 + (tu) + HClO4 solutions.
    16 schema:genre research_article
    17 schema:inLanguage en
    18 schema:isAccessibleForFree false
    19 schema:isPartOf N2c0708488b2a48d980bf91e2b25912da
    20 Ned486ed5dd294a179c1810f0f772fcd5
    21 sg:journal.1327871
    22 schema:name Structure of bismuth(III) complexes with thiourea according to EXAFS spectroscopy Data
    23 schema:pagination 461-464
    24 schema:productId N0417065664a84c07aa3b53226d23ab42
    25 N1444ca0d613b4015920a2eedb77e53d4
    26 Nbbda62487e584b7896b4807c2dc69455
    27 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017660820
    28 https://doi.org/10.1134/s0036024413030102
    29 schema:sdDatePublished 2019-04-10T19:55
    30 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    31 schema:sdPublisher N59ae3759a3564c7ca2fe45a8042ebdd5
    32 schema:url http://link.springer.com/10.1134/S0036024413030102
    33 sgo:license sg:explorer/license/
    34 sgo:sdDataset articles
    35 rdf:type schema:ScholarlyArticle
    36 N0417065664a84c07aa3b53226d23ab42 schema:name doi
    37 schema:value 10.1134/s0036024413030102
    38 rdf:type schema:PropertyValue
    39 N1444ca0d613b4015920a2eedb77e53d4 schema:name dimensions_id
    40 schema:value pub.1017660820
    41 rdf:type schema:PropertyValue
    42 N2c0708488b2a48d980bf91e2b25912da schema:issueNumber 3
    43 rdf:type schema:PublicationIssue
    44 N4c641454f0404dae9d67a6afa3146990 rdf:first sg:person.014374177255.13
    45 rdf:rest Nfbf54013463041f7a3a57075dbdafa33
    46 N59ae3759a3564c7ca2fe45a8042ebdd5 schema:name Springer Nature - SN SciGraph project
    47 rdf:type schema:Organization
    48 Nbbda62487e584b7896b4807c2dc69455 schema:name readcube_id
    49 schema:value 54253b6f6f6d9c8dc511a43a610d60f40d9a2199bf5761ab81a830c556cce9ee
    50 rdf:type schema:PropertyValue
    51 Ndc3ded39103b464e823a7812567235f4 rdf:first sg:person.07704211421.42
    52 rdf:rest N4c641454f0404dae9d67a6afa3146990
    53 Ned486ed5dd294a179c1810f0f772fcd5 schema:volumeNumber 87
    54 rdf:type schema:PublicationVolume
    55 Nfbf54013463041f7a3a57075dbdafa33 rdf:first sg:person.016134421043.54
    56 rdf:rest rdf:nil
    57 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    58 schema:name Chemical Sciences
    59 rdf:type schema:DefinedTerm
    60 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    61 schema:name Inorganic Chemistry
    62 rdf:type schema:DefinedTerm
    63 sg:journal.1327871 schema:issn 0036-0244
    64 0044-4537
    65 schema:name Russian Journal of Physical Chemistry A
    66 rdf:type schema:Periodical
    67 sg:person.014374177255.13 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
    68 schema:familyName Trubina
    69 schema:givenName S. V.
    70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014374177255.13
    71 rdf:type schema:Person
    72 sg:person.016134421043.54 schema:affiliation https://www.grid.ac/institutes/grid.412592.9
    73 schema:familyName Golovnev
    74 schema:givenName N. N.
    75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016134421043.54
    76 rdf:type schema:Person
    77 sg:person.07704211421.42 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
    78 schema:familyName Erenburg
    79 schema:givenName S. B.
    80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07704211421.42
    81 rdf:type schema:Person
    82 sg:pub.10.1134/s0036023612040250 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045742861
    83 https://doi.org/10.1134/s0036023612040250
    84 rdf:type schema:CreativeWork
    85 https://doi.org/10.1016/0022-1902(66)80241-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038036334
    86 rdf:type schema:CreativeWork
    87 https://doi.org/10.1016/j.ccr.2007.03.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053018551
    88 rdf:type schema:CreativeWork
    89 https://doi.org/10.1016/j.molliq.2004.07.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014344851
    90 rdf:type schema:CreativeWork
    91 https://doi.org/10.1016/s0025-5408(01)00734-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011375229
    92 rdf:type schema:CreativeWork
    93 https://doi.org/10.1021/cr980425s schema:sameAs https://app.dimensions.ai/details/publication/pub.1013908869
    94 rdf:type schema:CreativeWork
    95 https://doi.org/10.1021/ic000022m schema:sameAs https://app.dimensions.ai/details/publication/pub.1055537444
    96 rdf:type schema:CreativeWork
    97 https://doi.org/10.1139/v07-108 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042190912
    98 rdf:type schema:CreativeWork
    99 https://doi.org/10.2116/bunsekikagaku.29.11_785 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000469003
    100 rdf:type schema:CreativeWork
    101 https://www.grid.ac/institutes/grid.412592.9 schema:alternateName Siberian Federal University
    102 schema:name Siberian Federal University, Krasnoyarsk, Russia
    103 rdf:type schema:Organization
    104 https://www.grid.ac/institutes/grid.425759.8 schema:alternateName Nikolaev Institute of Inorganic Chemistry
    105 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
    106 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...