Mixed complexes of palladium(II) with 1-aminoethylidene-1,1-diphosphonic acid and glycine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-10

AUTHORS

A. N. Kozachkova, N. V. Tsaryk, A. V. Dudko, V. I. Pekhnyo, V. V. Trachevsky, A. B. Rozhenko, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

The complexing of palladium(II) with two biological active reagents: glycine (Gly, HA) and 1-aminoethylidene-1,1-diphosphonic acid (AEDP, H4L) at concentrations of chloride ions (0.15 mol/L) corresponding to physiological levels is studied by means of spectrophotometry, pH potentiometry, and 31P NMR spectroscopy. The formation constants for mixed complexes with compositions of [PdH2LA]− (logβ = 43.7) and [PdHLA]2− (logβ = 39.05) are determined. The both ligands are found to be coordinated to palladium(II) in a bidentant-cyclic manner: through amine nitrogen and the oxygen atom of the carboxyl group (in the case of Gly), or through the phosphonic group (in the case of AEDP). A diagram of the distribution of equilibrium concentrations of the complexes depending on pH is calculated for the system K2[PdCl4]: Gly: AEDP = 1: 1: 1. It is demonstrated that there are complexes with compositions of [PdHLA]2−, [PdA2], and [Pd(HL)2]4− in solutions with and pH 6–7. More... »

PAGES

1570-1576

References to SciGraph publications

  • 1985. PSEQUAD in COMPUTATIONAL METHODS FOR THE DETERMINATION OF FORMATION CONSTANTS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s0036024412100123

    DOI

    http://dx.doi.org/10.1134/s0036024412100123

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1030654580


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Other Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "National Academy of Sciences of Ukraine", 
              "id": "https://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680, Kiev, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kozachkova", 
            "givenName": "A. N.", 
            "id": "sg:person.0756213417.91", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0756213417.91"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "National Academy of Sciences of Ukraine", 
              "id": "https://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680, Kiev, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Tsaryk", 
            "givenName": "N. V.", 
            "id": "sg:person.01072442017.91", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072442017.91"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "National Academy of Sciences of Ukraine", 
              "id": "https://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680, Kiev, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Dudko", 
            "givenName": "A. V.", 
            "id": "sg:person.0710100217.67", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0710100217.67"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "National Academy of Sciences of Ukraine", 
              "id": "https://www.grid.ac/institutes/grid.418751.e", 
              "name": [
                "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680, Kiev, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Pekhnyo", 
            "givenName": "V. I.", 
            "id": "sg:person.0734146342.78", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0734146342.78"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Kurdjumov Institute of Metal Physics, 03142, Kiev, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Trachevsky", 
            "givenName": "V. V.", 
            "id": "sg:person.012676011725.88", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012676011725.88"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Organic Chemistry", 
              "id": "https://www.grid.ac/institutes/grid.464621.3", 
              "name": [
                "Institute of Organic Chemistry, 02660, Kiev, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Rozhenko", 
            "givenName": "A. B.", 
            "id": "sg:person.01337026420.99", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01337026420.99"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 117901, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Novotortsev", 
            "givenName": "V. M.", 
            "id": "sg:person.01013744635.03", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Russian Academy of Sciences", 
              "id": "https://www.grid.ac/institutes/grid.4886.2", 
              "name": [
                "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 117901, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Eremenko", 
            "givenName": "I. L.", 
            "id": "sg:person.0745631435.08", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1002/adfm.200600361", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005619470"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/adfm.200600361", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005619470"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/adfm.200600361", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005619470"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-1-4684-4934-1_8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1023803840", 
              "https://doi.org/10.1007/978-1-4684-4934-1_8"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0020-1693(00)91874-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034558360"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b914379c", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034866929"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b914379c", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034866929"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00230a050", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055716147"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2012-10", 
        "datePublishedReg": "2012-10-01", 
        "description": "The complexing of palladium(II) with two biological active reagents: glycine (Gly, HA) and 1-aminoethylidene-1,1-diphosphonic acid (AEDP, H4L) at concentrations of chloride ions (0.15 mol/L) corresponding to physiological levels is studied by means of spectrophotometry, pH potentiometry, and 31P NMR spectroscopy. The formation constants for mixed complexes with compositions of [PdH2LA]\u2212 (log\u03b2 = 43.7) and [PdHLA]2\u2212 (log\u03b2 = 39.05) are determined. The both ligands are found to be coordinated to palladium(II) in a bidentant-cyclic manner: through amine nitrogen and the oxygen atom of the carboxyl group (in the case of Gly), or through the phosphonic group (in the case of AEDP). A diagram of the distribution of equilibrium concentrations of the complexes depending on pH is calculated for the system K2[PdCl4]: Gly: AEDP = 1: 1: 1. It is demonstrated that there are complexes with compositions of [PdHLA]2\u2212, [PdA2], and [Pd(HL)2]4\u2212 in solutions with and pH 6\u20137.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1134/s0036024412100123", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1327871", 
            "issn": [
              "0036-0244", 
              "0044-4537"
            ], 
            "name": "Russian Journal of Physical Chemistry A", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "10", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "86"
          }
        ], 
        "name": "Mixed complexes of palladium(II) with 1-aminoethylidene-1,1-diphosphonic acid and glycine", 
        "pagination": "1570-1576", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "9208d113c630a8e103efa21e6570c654d29786080c762d7c85c4ba1aadb8696f"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s0036024412100123"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1030654580"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s0036024412100123", 
          "https://app.dimensions.ai/details/publication/pub.1030654580"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T16:40", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000506.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1134/S0036024412100123"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036024412100123'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036024412100123'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036024412100123'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036024412100123'


     

    This table displays all metadata directly associated to this object as RDF triples.

    134 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s0036024412100123 schema:about anzsrc-for:03
    2 anzsrc-for:0399
    3 schema:author Nc8d26e51a5ca4b4bb4f936478f8ea11b
    4 schema:citation sg:pub.10.1007/978-1-4684-4934-1_8
    5 https://doi.org/10.1002/adfm.200600361
    6 https://doi.org/10.1016/s0020-1693(00)91874-7
    7 https://doi.org/10.1021/ja00230a050
    8 https://doi.org/10.1039/b914379c
    9 schema:datePublished 2012-10
    10 schema:datePublishedReg 2012-10-01
    11 schema:description The complexing of palladium(II) with two biological active reagents: glycine (Gly, HA) and 1-aminoethylidene-1,1-diphosphonic acid (AEDP, H4L) at concentrations of chloride ions (0.15 mol/L) corresponding to physiological levels is studied by means of spectrophotometry, pH potentiometry, and 31P NMR spectroscopy. The formation constants for mixed complexes with compositions of [PdH2LA]− (logβ = 43.7) and [PdHLA]2− (logβ = 39.05) are determined. The both ligands are found to be coordinated to palladium(II) in a bidentant-cyclic manner: through amine nitrogen and the oxygen atom of the carboxyl group (in the case of Gly), or through the phosphonic group (in the case of AEDP). A diagram of the distribution of equilibrium concentrations of the complexes depending on pH is calculated for the system K2[PdCl4]: Gly: AEDP = 1: 1: 1. It is demonstrated that there are complexes with compositions of [PdHLA]2−, [PdA2], and [Pd(HL)2]4− in solutions with and pH 6–7.
    12 schema:genre research_article
    13 schema:inLanguage en
    14 schema:isAccessibleForFree false
    15 schema:isPartOf N8c6a421e9645495491f34349437b2ae5
    16 Ne679dbebb96a44819ef59f1e5542cb8b
    17 sg:journal.1327871
    18 schema:name Mixed complexes of palladium(II) with 1-aminoethylidene-1,1-diphosphonic acid and glycine
    19 schema:pagination 1570-1576
    20 schema:productId N3b794911217f4d6fa0267ee51a7601ec
    21 Na0c501a6e19d4828aae6bef0dda8dae2
    22 Ne007bff539194706adc5b8b5e1098059
    23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030654580
    24 https://doi.org/10.1134/s0036024412100123
    25 schema:sdDatePublished 2019-04-10T16:40
    26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    27 schema:sdPublisher N84e367af737741a4991ccee4a32b6771
    28 schema:url http://link.springer.com/10.1134/S0036024412100123
    29 sgo:license sg:explorer/license/
    30 sgo:sdDataset articles
    31 rdf:type schema:ScholarlyArticle
    32 N0d38de527a3448b983fb4c1cc95cabee rdf:first sg:person.01072442017.91
    33 rdf:rest N24176ea317724ba09333185313be4023
    34 N24176ea317724ba09333185313be4023 rdf:first sg:person.0710100217.67
    35 rdf:rest Nc8e391eaaa864c7db5f2d6c7ab152e2f
    36 N29a42ca4b6fe4569bdab00d3759b626f rdf:first sg:person.01013744635.03
    37 rdf:rest Nfdda331f10f243a69728db761e4b2534
    38 N3b794911217f4d6fa0267ee51a7601ec schema:name doi
    39 schema:value 10.1134/s0036024412100123
    40 rdf:type schema:PropertyValue
    41 N543d03ad9bc648378cfeef4574d7cad2 schema:name Kurdjumov Institute of Metal Physics, 03142, Kiev, Ukraine
    42 rdf:type schema:Organization
    43 N84e367af737741a4991ccee4a32b6771 schema:name Springer Nature - SN SciGraph project
    44 rdf:type schema:Organization
    45 N8c6a421e9645495491f34349437b2ae5 schema:issueNumber 10
    46 rdf:type schema:PublicationIssue
    47 Na0c501a6e19d4828aae6bef0dda8dae2 schema:name dimensions_id
    48 schema:value pub.1030654580
    49 rdf:type schema:PropertyValue
    50 Nbb4d40d83a8a4ddab2a5e29d74d1c013 rdf:first sg:person.012676011725.88
    51 rdf:rest Nd0daf1fe1e3c4398808c8d4b4abce0d8
    52 Nc8d26e51a5ca4b4bb4f936478f8ea11b rdf:first sg:person.0756213417.91
    53 rdf:rest N0d38de527a3448b983fb4c1cc95cabee
    54 Nc8e391eaaa864c7db5f2d6c7ab152e2f rdf:first sg:person.0734146342.78
    55 rdf:rest Nbb4d40d83a8a4ddab2a5e29d74d1c013
    56 Nd0daf1fe1e3c4398808c8d4b4abce0d8 rdf:first sg:person.01337026420.99
    57 rdf:rest N29a42ca4b6fe4569bdab00d3759b626f
    58 Ne007bff539194706adc5b8b5e1098059 schema:name readcube_id
    59 schema:value 9208d113c630a8e103efa21e6570c654d29786080c762d7c85c4ba1aadb8696f
    60 rdf:type schema:PropertyValue
    61 Ne679dbebb96a44819ef59f1e5542cb8b schema:volumeNumber 86
    62 rdf:type schema:PublicationVolume
    63 Nfdda331f10f243a69728db761e4b2534 rdf:first sg:person.0745631435.08
    64 rdf:rest rdf:nil
    65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    66 schema:name Chemical Sciences
    67 rdf:type schema:DefinedTerm
    68 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
    69 schema:name Other Chemical Sciences
    70 rdf:type schema:DefinedTerm
    71 sg:journal.1327871 schema:issn 0036-0244
    72 0044-4537
    73 schema:name Russian Journal of Physical Chemistry A
    74 rdf:type schema:Periodical
    75 sg:person.01013744635.03 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    76 schema:familyName Novotortsev
    77 schema:givenName V. M.
    78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03
    79 rdf:type schema:Person
    80 sg:person.01072442017.91 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
    81 schema:familyName Tsaryk
    82 schema:givenName N. V.
    83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072442017.91
    84 rdf:type schema:Person
    85 sg:person.012676011725.88 schema:affiliation N543d03ad9bc648378cfeef4574d7cad2
    86 schema:familyName Trachevsky
    87 schema:givenName V. V.
    88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012676011725.88
    89 rdf:type schema:Person
    90 sg:person.01337026420.99 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
    91 schema:familyName Rozhenko
    92 schema:givenName A. B.
    93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01337026420.99
    94 rdf:type schema:Person
    95 sg:person.0710100217.67 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
    96 schema:familyName Dudko
    97 schema:givenName A. V.
    98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0710100217.67
    99 rdf:type schema:Person
    100 sg:person.0734146342.78 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
    101 schema:familyName Pekhnyo
    102 schema:givenName V. I.
    103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0734146342.78
    104 rdf:type schema:Person
    105 sg:person.0745631435.08 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
    106 schema:familyName Eremenko
    107 schema:givenName I. L.
    108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08
    109 rdf:type schema:Person
    110 sg:person.0756213417.91 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
    111 schema:familyName Kozachkova
    112 schema:givenName A. N.
    113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0756213417.91
    114 rdf:type schema:Person
    115 sg:pub.10.1007/978-1-4684-4934-1_8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023803840
    116 https://doi.org/10.1007/978-1-4684-4934-1_8
    117 rdf:type schema:CreativeWork
    118 https://doi.org/10.1002/adfm.200600361 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005619470
    119 rdf:type schema:CreativeWork
    120 https://doi.org/10.1016/s0020-1693(00)91874-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034558360
    121 rdf:type schema:CreativeWork
    122 https://doi.org/10.1021/ja00230a050 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055716147
    123 rdf:type schema:CreativeWork
    124 https://doi.org/10.1039/b914379c schema:sameAs https://app.dimensions.ai/details/publication/pub.1034866929
    125 rdf:type schema:CreativeWork
    126 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
    127 schema:name Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680, Kiev, Ukraine
    128 rdf:type schema:Organization
    129 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
    130 schema:name Institute of Organic Chemistry, 02660, Kiev, Ukraine
    131 rdf:type schema:Organization
    132 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
    133 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 117901, Moscow, Russia
    134 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...