Unusually high efficiency of the separation of polymers by hydrodynamic chromatography on hollow capillary columns View Full Text


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Article Info

DATE

2012-07

AUTHORS

A. A. Korolev, E. N. Viktorova, V. A. Orekhov, A. A. Kurganov

ABSTRACT

A series of polystyrene standards was separated by means of hydrodynamic chromatography on a open capillary with a length of 5 m (active zone is 4.5 m) and an inner diameter of 2 μm. Unusually high efficiency in the separation of polymers with masses of up to 500 kDa was noticed: 1.5 × 106 theoretical plates at a retention time of ∼70 min for a sample of polystyrene with a mass of 390 kDa. It was established that the column efficiency decreases rapidly for polymers with a mass above 500 kDa. A calibration curve for polystyrene standards was constructed. It was shown that, in contrast to the models described in the literature, it is described by a simple two-term expression without quadratic terms. It is concluded that hydrodynamic chromatography is a technique complementary to exclusion chromatography, especially in the separation of high-molecular polymers. More... »

PAGES

1161-1164

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024412070096

DOI

http://dx.doi.org/10.1134/s0036024412070096

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036488385


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