The adsorption of hetero- and alicyclic thiophene derivatives from water-acetonitrile solutions on the surface of porous graphitic carbon under high-performance ... View Full Text


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Article Info

DATE

2012-05-24

AUTHORS

B. R. Saifutdinov, N. S. Emel’yanova, S. V. Kurbatova, A. A. Pimerzin

ABSTRACT

The adsorption of hetero- and alicyclic thiophene derivatives synthesized for the first time from water-acetonitrile solutions with various compositions on the surface of porous graphitic carbon was studied by the high-performance liquid chromatography method. The retention factor and Henry adsorption constant values and equilibrium constants of quasi-chemical reactions of the adsorption and solvation of the heterocyclic compounds studied were calculated using the Lanin-Nikitin equation. The influence of the structure of hetero- and alicyclic thiophene derivative molecules on their adsorption on the surface of porous graphitic carbon and solvation in water-acetonitrile solutions was discussed. The Lanin-Nikitin model was found to be more informative in the interpretation of the adsorption-chromatographic experiment data compared with the Snyder-Soczewinski and Scott-Kucera models. More... »

PAGES

1152-1160

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024412060234

DOI

http://dx.doi.org/10.1134/s0036024412060234

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052925439


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