Catalytic dehydrogenation of propanol-2 on Na-Zr phosphates containing Cu, Co, and Ni View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-06

AUTHORS

E. I. Povarova, A. I. Pylinina, I. I. Mikhalenko

ABSTRACT

The dehydrogenation of propanol-2 on sodium-zirconium phosphates (NZP) with the composition Na1 − 2xMxZr2(PO4)3 (x = 0.125 and 0.25) in which Na+ ions were replaced by M2+ = Co2+, Ni2+, and Cu2+ ions was studied. The experimental reaction activation energy Ea decreased while transition through the T* = 310−340°C temperature; above this temperature, the electrophysical and crystallographic properties of the material changed. These changes were explained by the reversible transfer of Me2+ ions from position M1 to M2 in the NZP lattice. Me2+ centers with different alcohol adsorption forms at T < T* (one-point) and T > T* (two-point) participated in the dehydrogenation reaction. For the first form, Ea and the logarithm of the preexponential factor linearly correlated with the ionic radius of M2+. The activity of M-NZP catalysts altered in repeated experiments and in cases when the direction of temperature variations changed. More... »

PAGES

935-941

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024412060210

DOI

http://dx.doi.org/10.1134/s0036024412060210

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024404835


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