Dehydrogenation of butyl alcohols on NASICON-type solid electrolytes of Na1 − 2xCuxZr2(PO4)3 composition View Full Text


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Article Info

DATE

2011-12

AUTHORS

A. I. Pylinina, I. I. Mikhalenko

ABSTRACT

Characteristics of the catalytic activity in the dehydration of butanols of copper-containing sodium-zirconium-phosphates (NZPs), in which Na+ ions substitute for Cu2+ ions are obtained. It was found that in the 100–370°C region, the action energy of the reaction falls upon the transition through temperature T* ∼ 300°C, above which the electrophysical and crystallographic properties of phosphates change. The observed dependences are explained by the center (which consists of copper with various positions in the phosphate network at T < T* and T > T*) taking part in the formation of carbonyl compounds. This indicates the presence of a ligand effect, i.e., to structural sensitivity of the dehydration reaction in the case of Cu-NZP catalysts. More... »

PAGES

2109

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024411110252

DOI

http://dx.doi.org/10.1134/s0036024411110252

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041764547


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