Reactions between a superoxide anion and alkyl bromides in dimethyl sulfoxide View Full Text


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Article Info

DATE

2011-08-27

AUTHORS

A. I. Pomeshchenko, I. V. Efimova, A. F. Dmitruk, O. M. Zarechnaya, I. A. Opeida

ABSTRACT

The activation parameters of the reactions between a superoxide anion (O2·−) and alkyl bromides are measured. An ab initio study of the transition states for various mechanisms of this reaction is performed. The mechanism of radical separation in a polar solvent becomes competitive upon an increase in the number of alkyl groups in an alkyl bromide molecule and depends on their arrangement relative to a reaction center. More... »

PAGES

1737

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024411100189

DOI

http://dx.doi.org/10.1134/s0036024411100189

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020406683


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